Boron has lesser ionization enthalpy than Beryllium, because:
| 1. | It is easier to remove electrons from p - a subshell than a filled s - subshell. |
| 2. | The s-electron can be removed easier than the p-electron. |
| 3. | Ionization enthalpy decreases with an increase in atomic number. |
| 4. | Ionization enthalpy increases along the period. |
| Elements | |||
| I | 520 | 7300 | -60 |
| II | 419 | 3051 | -48 |
| III | 1681 | 3374 | -328 |
| IV | 1008 | 1846 | -295 |
| V | 2372 | 5251 | +48 |
| VI | 738 | 1451 | -40 |
The energy of an electron in the ground state of the hydrogen atom is . The ionization enthalpy of atomic hydrogen in terms of J is:
1. 2.81 × 106 J mol
2. 1.31 × 106 J mol
3. 2.31 × 106 J mol
4. 1.81 × 106 J mol
The explanation for the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthalpy is higher than that of magnesium would be :
| 1. | Pressure and volume |
| 2. | Lustre and brightness |
| 3. | Atomic size and effective nuclear charge |
| 4. | Availability in nature |
The first ionization enthalpy values (in kJ mol–1) of group 13 elements are :
| B | Al | Ga | In | Tl |
| 801 | 577 | 579 | 558 | 589 |
The explanation for the deviation from the general trend can be:
1. B has filled subshells, giving it unusually high ionization energy
2. Ga has a filled 3d¹⁰ subshell, increasing the effective nuclear charge
3. Indium has a very small atomic size, lowering its ionization energy
4. Tl has an unusually low nuclear charge, decreasing ionization energy
The values of the first ionization enthalpies for two isotopes would be:
| 1. | Same. |
| 2. | Different. |
| 3. | Same values but positive for the first and negative for the second. |
| 4. | Same values but negative for the first and positive for the second. |
The reactivity of alkali metals increases, whereas halogen decreases down the group, because:
| 1. | On moving down, ionization enthalpy decreases in group 1 while the electron gain enthalpy becomes less negative in group 17. |
| 2. | On moving down, ionization enthalpy increases in group 1 while the electron gain enthalpy becomes less negative in group 17. |
| 3. | On moving down, ionization enthalpy increases in group 1 while the electron gain enthalpy becomes less positive in group 17. |
| 4. | On moving down, ionization enthalpy decreases in group 17 while the electron gain enthalpy becomes less negative in group 1. |
1st (∆H1) and 2nd (∆H2) Ionization Enthalpies (in kJ mol–1) and the (∆egH) Electron Gain Enthalpy (in kJ mol–1) of a few elements are given below:
| Elements | ΔH1 | ΔH2 | ΔegH |
| I | 520 | 7300 | –60 |
| II | 419 | 3051 | –48 |
| III | 1681 | 3374 | –328 |
| IV | 1008 | 1846 | –295 |
| V | 2372 | 5251 | +48 |
| VI | 738 | 1451 | –40 |
The most reactive metal is:
| 1. | VI | 2. | III |
| 3. | I | 4. | II |
The incorrect statement about ionization enthalpy is:
| 1. | Ionization enthalpy increases for each successive electron. |
| 2. | Noble gases have the highest ionization enthalpy. |
| 3. | A big jump in ionization enthalpy indicates a stable configuration. |
| 4. | Ionization enthalpy of oxygen is higher than that of nitrogen. |
What is the difference between electronegativity and electron gain enthalpy?
| 1. | An element has a constant value of the electron gain enthalpy but not of electronegativity. |
| 2. | There is no difference between these two terms. |
| 3. | An element has a constant value of electronegativity but not of electron gain enthalpy. |
| 4. | None of the above. |