Atoms and ions having the same number of electrons are called isoelectronic species.
(i) F–ion has 9 + 1 = 10 electrons. Thus, the species isoelectronic with it will also have
10 electrons. Some of its isoelectronic species are Na+ ion (11 – 1 = 10 electrons), Ne (10
electrons), O–ion (8 + 2 = 10 electrons), and Al ion (13 – 3 = 10 electrons).
(ii)Ar has 18 electrons. Thus, the species isoelectronic with it will also have 18 electrons.
Some of its isoelectronic species are S2–ion (16 + 2 = 18 electrons), Cl–ion (17 + 1 = 1
electrons), K+ ion (19 – 1 = 18 electrons), and Ca2+ ion (20 – 2 = 18 electrons).
(iii) Mg ion has 12 – 2 = 10 electrons. Thus, the species isoelectronic with it will
also have 10 electrons. Some of its isoelectronic species are F–
ion (9 + 1 = 10 electrons),
Ne (10 electrons), O2–ion (8 + 2 = 10 electrons), and Al3+ ion (13 – 3 = 10 electrons).
(iv) Rb ion has 37 – 1 = 36 electrons. Thus, the species isoelectronic with it will
also have 36 electrons. Some of its isoelectronic species are Br–ion (35 + 1 = 36
electrons), Kr (36 electrons), and Sr2+ ion (38 – 2 = 36 electrons).
3.12 Consider the following species :
N3–, O2–, F–, Na+, Mg2+ and Al3+
(a) What is common in them?
(b) Arrange them in the order of increasing ionic radii.
Atoms and ions having the same number of electrons are called isoelectronic species.
(i) F–ion has 9 + 1 = 10 electrons. Thus, the species isoelectronic with it will also have
10 electrons. Some of its isoelectronic species are Na+ ion (11 – 1 = 10 electrons), Ne (10
electrons), O–ion (8 + 2 = 10 electrons), and Al ion (13 – 3 = 10 electrons).
(ii)Ar has 18 electrons. Thus, the species isoelectronic with it will also have 18 electrons.
Some of its isoelectronic species are S2–ion (16 + 2 = 18 electrons), Cl–ion (17 + 1 = 1
electrons), K+ ion (19 – 1 = 18 electrons), and Ca2+ ion (20 – 2 = 18 electrons).
(iii) Mg ion has 12 – 2 = 10 electrons. Thus, the species isoelectronic with it will
also have 10 electrons. Some of its isoelectronic species are F–
ion (9 + 1 = 10 electrons),
Ne (10 electrons), O2–ion (8 + 2 = 10 electrons), and Al3+ ion (13 – 3 = 10 electrons).
(iv) Rb ion has 37 – 1 = 36 electrons. Thus, the species isoelectronic with it will
also have 36 electrons. Some of its isoelectronic species are Br–ion (35 + 1 = 36
electrons), Kr (36 electrons), and Sr2+ ion (38 – 2 = 36 electrons).