Which of the following reactions are disproportionation reactions?

(i)Cu+Cu2++Cu
(ii)3MnO4+4H+2MnO4+MnO2+2H2O
(iii)2KMnO4K2MnO4+MnO2+O2
(iv)2MnO4+3Mn2++2H2O5MnO2+4H+

1.  (i)

2.  (i) , (ii) and (iii)

3.  (ii) , (iii) and (iv)

4.  (i) and (iv)

NEETprep Answer: 
The reaction in which oxidation as well as reduction, occur upon same atom simultaneously is known as disproportionation reaction.