1.34 A welding fuel gas contains carbon and hydrogen only. Burning a small sample of it in oxygen gives 3.38 g carbon dioxide, 0.690 g of water, and no other products. A volume of 10.0 L (measured at STP) of this welding gas is found to weigh 11.6 g. Calculate
(i) empirical formula,
(ii) molar mass of the gas, and
(iii) molecular formula.
(i) 1 mole (44 g) of CO2 contains 12 g of carbon.
3.38 g of CO2 will contain carbon =
= 0.9217 g
18 g of water contains 2 g of hydrogen.
0.690 g of water will contain hydrogen =
= 0.0767 g
Since carbon and hydrogen are the only constituents of the compound, the total mass of the compound is:
= 0.9217 g + 0.0767 g
= 0.9984 g
Percent of C in the compound =
= 92.32%
Percent of H in the compound =
= 7.68%
Moles of carbon in the compound =
= 7.69
Moles of hydrogen in the compound =
= 7.68
Ratio of carbon to hydrogen in the compound = 7.69: 7.68 = 1: 1
Hence, the empirical formula of the gas is CH.
(ii) Given,
Weight of 10.0L of the gas (at S.T.P) = 11.6 g
Weight of 22.4 L of gas at STP =
= 25.984 g
≈ 26 g
Hence, the molar mass of the gas is 26 g.
(iii) Empirical formula mass of CH = 12 + 1 = 13 g
n = 2
Molecular formula of gas =
=
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