The relative reactivities of acyl compounds towards nudeophilic substitution are in the order of

1.  Acyl chloride > Acid anhydride > Ester > Amide

2.  Ester > Acyl chloride > Amide >Acid anhydride

3.  Acid anhydride > Amide > Ester > Acyl chloride

4.  Acyl chloride > Ester > Acid anhydride > Amide

Acetophenone when reacted with a base, C₂H₅ONa, yields a stable compound which has the structure

1.  

2.  

3.  

4.  

A reaction among the following tht donot result in the formation of carbon-carbon bonds is -

1. Reimer-tiemann reaction

2. Cannizzaro reaction

3. Wurtz reaction

4. Friedel-Crafts acylation

Among the given compounds, the most susceptible to nucleophilic attack at the carbonyl group is

1. $C{H}_{3}COOC{H}_3$

2. $C{H}_{3}CON{H}_2$

3. $C{H}_{3}COOCOC{H}_3$

4. $C{H}_{3}COCl$

Which one is a nucleophilic substitution reaction among the following?

1.  $\mathrm{RCHO}+\mathrm{R}\text{'}\mathrm{MgX}\to \mathrm{R}-\underset{\mathrm{OH}}{\underset{|}{\mathrm{CH}}}-\mathrm{R}\text{'}$

2.  ${\mathrm{CH}}_3-{\mathrm{CH}}_2-\stackrel{{\mathrm{CH}}_3}{\stackrel{|}{\mathrm{CH}}}-{\mathrm{CH}}_2\mathrm{Br}+{\mathrm{NH}}_3\to {\mathrm{CH}}_3-{\mathrm{CH}}_2-\stackrel{{\mathrm{CH}}_3}{\stackrel{|}{\mathrm{CH}}}-{\mathrm{CH}}_2{\mathrm{NH}}_2$

3.  ${\mathrm{CH}}_3\mathrm{CHO}+\mathrm{HCN}\to {\mathrm{CH}}_3\mathrm{CH}\left(\mathrm{OH}\right)\mathrm{CN}$

4.  ${\mathrm{CH}}_3-\mathrm{CH}={\mathrm{CH}}_2+{\mathrm{H}}_2\mathrm{O}\stackrel{{\mathrm{H}}^{+}}{\to }{\mathrm{CH}}_3-\underset{\mathrm{OH}}{\underset{|}{\mathrm{CH}}}-{\mathrm{CH}}_3$

In a set of reactions, m-bromobenzoic acid gave a product D. The product D is:

1.		2.
3.		4.

Clemmensen reduction of a ketone is carried out in the presence of which of the following?

1.  $\mathrm{Zn}$-$\mathrm{Hg}$ with $\mathrm{HCl}$

2.  ${\mathrm{LiAlH}}_4$

3.  ${\mathrm{H}}_2$ and $\mathrm{Pt}$ as catalyst

4.  Glycol with $\mathrm{KOH}$

${\mathrm{CH}}_3\mathrm{CHO}$ and ${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{CH}}_2\mathrm{CHO}$ can be distinguished chemically by-

1. Benedict test

2. Iodoform test

3. Tollen's reagent test

4. Fehling solution test

The correct order of decreasing acid strength of trichloroacetic acid (A), trifluoroacetic acid (B), acetic acid (C) and formic acid (D)

1. B > A > D > C

2. B > D > C > A

3. A > B > C > D

4. A > C > B >D