Aniline was acetylated and an acetanilide is formed. The acetanilide on nitration followed by alkaline hydrolysis gave:

1. o-Nitroacetanilide

2. o- and p-Nitroaniline

3. m-Nitroaniline

4. Acetanilide

In the chemical reactions,

$\underset{\mathrm{HCl}, 278 \mathrm{K}}{\overset{{\mathrm{NaNO}}_2}{\to }}A\stackrel{HB{F}_4}{\to }B$

the compounds 'A' and 'B' respectively are:

1. nitrobenzene and chlorobenzene

2. nitrobenzene and flurobenzene

3. phenol and benzene

4. benzene diazonium chloride and fluorobenzene

Which of the following reactions is appropriate for converting acetamide to methanamine ?

(1) Carbylamine reaction

(2) Hoffmann Bromamide reaction

(3) Stephens reaction

(4) Gabriels phthalimide synthesis

Which one of the following nitro-compounds does not rect with nitrous acid ?

A given nitrogen-containing aromatic compound a reacts with Sn/HCl, followed by HNO₂ to give an unsatable compound B.B, on treament with phenol, forms a beautiful coloured compound C with the molecular formula C₁₂H₁₀N₂O. The structure of compound A is

The correct statement regarding the basicity of arylamines is

(1) Arylamines are generally more basic than alkylamines because the nitrogen lone-pair electrons are not delocalized by interaction with the aromatic ring p-electron system.

(2) Arylamines are generally more basic than alkylamines because of aryl group.

(3) Arylamines are generally more basic than alkylamines, because the nitrogen atom in arylamines is sp-hybridized

(4) Arylamines are generally less basic than alkylamines because the nitrogen lone-pair electrons are delocalized by interaction with the aromatic ring p-electron system.

Which of the following will be most stable diazonium salt $R{\mathrm{N}}_2^{+}{X}^{-}$ ?

(a) ${\mathrm{CH}}_3{\mathrm{N}}_2^{+}{\mathrm{X}}^{-}$

(b) ${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{N}}_2^{+}{\mathrm{X}}^{-}$

(c) ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{N}}_2^{+}{\mathrm{X}}^{-}$

(d) ${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{CH}}_2{\mathrm{N}}_2^{+}{X}^{-}$

Which of the following is more basic than aniline ?

1. Diphenylamine

2. Triphenylamine

3. p-nitroaniline

4. Benzylamine

Which of the following compounds will not give Hoffmann bromamide reaction?

1.         

2.  

3.       

4.  

Identify the major product (A) formed in the following reaction/\.

1.               2.  

3.        4.