In the Carius method, 0.468 grams of an organic sulphur compound gives 0.668 grams of barium sulphate. The percentage of sulphur in the given compound is -
1. | 19.59% | 2. | 25.40% |
3. | 09.24% | 4. | 27.59% |
The most stable carbocation among the following is-
1.
2.
3.
4.
is more stable than because :
1. | NO2 shows +I effect |
2. | NO2 shows -I effect |
3. | NO2 decreases the positive charge on the compound |
4. | Ethyl group increases positive charge on the compound |
Alkyl groups act as electron donors when attached to a π system due to:
1. | Inductive effect | 2. | Mesomeric effect |
3. | Resonance | 4. | Hyperconjugation |
An electrophile among the following is :
1. | 2. | ||
3. | 4. | Carbonyl group |
Which of the following reactions is an elimination reaction?
1. | CH3CH2Br + HS- → CH3CH2SH + Br- |
2. | ( CH3)2C=CH2 + HCl → (CH3)2ClC-CH3 |
3. | CH3CH2Br+HO- → CH2=CH2 + Br-+H2O |
4. | (CH3)3C-CH2OH + HBr → (CH3)2CBrCH2CH3 + H2O |
Free radical formation will take place in :
1. | |
2. | |
3. | |
4. |
The effect that can explain the given order of acidity of the carboxylic acids is-
Cl3CCOOH > Cl2CHCOOH > ClCH2COOH
1. +I effect
2. -I effect
3. +E effect
4. -E effect
The purification method based on the difference in solubilities of the compound and the impurities in a solvent is -
1. Crystallisation
2. Distillation
3. Chromatography
4. Isolation