At 25° C molar conductance of 0.1 molar aqueous solution of ammonium hydroxide is

9.54 ohm¹cm²mol^-1 and at infinite dilution its molar conductance is 238 ohm¹cm²mol^-1.

The degree of ionisation of ammonium hydroxide at the same concentration and

temperature is

1. 2.080%

2. 20.800%

3. 4.008%

4. 40.800%

A button cell used in watches functions as following

Zn(s) + Ag₂O(s) + H₂O (l) $\rightleftharpoons$2Ag(s) + Zn²⁺(aq) + 2OH^-(aq)

If half cell potentials are

$$\begin{gathered} {{\mathrm{Zn}}^{2+}}_{\left(\mathrm{aq}\right)} +\hspace{0.17em}2{\mathrm{e}}^{-} \to {\mathrm{Zn}}_{\left(\mathrm{x}\right)}; {\mathrm{E}}^{\mathrm{o}} = -0.76\mathrm{V} \\ {\mathrm{Ag}}_2{\mathrm{O}}_{\left(\mathrm{s}\right)} + {\mathrm{H}}_2{\mathrm{O}}_{\left(\mathrm{l}\right)} + 2{\mathrm{e}}^{-} \to 2{\mathrm{Ag}}_{\left(\mathrm{s}\right)} + 2{{\mathrm{OH}}^{-}}_{\left(\mathrm{aq}\right)}; \\ {\mathrm{E}}^{\mathrm{o}} = 0.34\mathrm{V} \end{gathered}$$

The cell potential will be

1. 0.84 V

2. 1.34 V

3. 1.10 V

4. 0.42 V

Limiting molar conductivity of NH₄OH (i.e Åm(NH₄OH)) is equal to:-

1. Å_m (NH₄Cl)+Å_m(NaCl)-Å_m(NaOH) 

2. Å_m(NaOH)+Å_m(NaCl)-Å_m(NH₄Cl)

3. Å_m(NH₄OH)+Å_m(NH₄Cl)-Å_m(HCl)

4. Å(NH₄Cl)+Å(NaOH)-Å(NaCl)

Standard free energies of formation (in kJ/mol) at 298 K are -237.2, -394.4 and -8.2 for H₂O(l), CO₂(g) and pentane (g), respectively. The value of E°_cell for the pentane-oxygen fuel cell is

(1) 1.968 V

(2) 2.0968 V

(3) 1.0968 V

(4) 0.0968 V

The efficiency of a fuel cell is given by:

$\left(\mathrm{a}\right) ∆\mathrm{H}/∆\mathrm{G} \left(\mathrm{b}\right) ∆\mathrm{G}/∆\mathrm{S}$
$\left(\mathrm{c}\right) ∆\mathrm{G}/∆\mathrm{H} \left(\mathrm{d}\right) ∆\mathrm{S}/∆\mathrm{G}$

The weight of silver (atomic weight = 108) displaced by a quantity of electricity which displaces 5600 mL of O₂ at STP will be : 

1. 5.4 g

2. 10.8 g

3. 54.0 g

4. 108.0 g

Aqueous solution of which of the following compounds is the best conductor of electric

current?

1. Acetic acid, C₂H₄O₂

2. Hydrochloric acid, HCl

3. Ammonia, NH₃

4. Fructose, C₆H₁₂O₆

A device that converts energy of the combustion of fuels like hydrogen and methane, directly

into electrical energy is known as:

1. Fuel cell

2. Electrolytic cell

3. Dynamo

4. Ni-Cd cell

The pressure of H₂ required to make the potential of H₂-electrode zero in pure water at

298 K is

1. 10^-12 atm

2. 10^-10 atm

3. 10^-4 atm

4. 10^-14 atm

Zinc can be coated on iron to produce galvanised iron but the reverse is not possible. It is because

(1) zinc is lighter than iron

(2) zinc has lower melting point than iron

(3) zinc has lower negative electrode potential than iron

(4) zinc has higher negative electrode potential than iron