The splitting of spectral lines in a magnetic field, arising out of the orbital motion of electrons only and the further splitting due to spin motion are respectively called

1. Zeeman and Stark effects

2. Zeeman and anomalous Zeeman effects

3. Stark and Zeeman effects

4. Zeeman and Kerr effects

A photon of wavelength 300 nm causes the emission of two photons. If the wavelength of one of them is 700 nm. What is the wavelength of the other photon?

1. 525 nm

2. 600 nm

3. 450 nm

4. 300 nm

The electronic transition in the hydrogen atom that emits maximum energy is:

1. 2 $\to$ 1

2. 1 $\to$ 4

3. 4 $\to$ 3

4. 3 $\to$ 2

The spectrum of He-atom may be considered similar to the spectrum of - 

1. H

2. Li⁺

3. Na

4. He⁺

The frequency ratio between violet (400nm) and red (750nm) radiations in the visible spectrum, is-

1. 8/15

2. 4/15

3. 15/8

4. None of these

The Compton wavelength for an electron is  $\left(\frac{h}{m_{0}c}\right)$

0.024 Å 

calculate $∆\lambda$= $\left(\frac{h}{m_{0}c}\right)$(1- cos θ) for a scattering angle  θ = $\mathrm{\pi }$/3. What is the maximum value for $∆\lambda$ ?

1. 0.024 Å, 0.048 Å

2. 0.012 Å, 0.048 Å

3. 0.012 Å, 0.024 Å

4. 0.006 Å, 0.012 Å

Positronium is an unstable complex of electron and positron, both of the same mass, but opposite charge. Apply Bohr's theory of hydrogen atom to this system and obtain the energy required to separate the electron from the positron.

(ionization energy of the ground state hydrogen atom= 13.62eV.) Express the result in KJmol^-1

1. 550 KJmol^-1

2. 657 KJmol^-1

3. 851 KJmol^-1

4. 720 KJmol^-1

The total spin resulting for a 3d⁷ configuration is 

1. 3/2

2. 1/2

3. 2

4. 1

Supposing the energy of the fourth shell for the hydrogen atom is -50a.u. (Arbitrary unit). What would be its ionization potential-

1. 50

2. 800

3. 15.4

4. 20.8

An element with atomic mass Z consists of two isotopes of mass number Z-1 and Z + 2. The percentage abundance of the heavier isotope is -

1. 0.25

2. 33.3

3. 66.6

4. 75