The correct order of increasing [H₃O⁺] in the following aqueous solutions is:

1. 0.01 M H₂S < 0.01 M H₂SO₄<0.01 M NaCl<0.01M NaNO₂

2. 0.01 M NaCl< 0.01 M NaNO₂<0.01 M H₂S< 0.01 M H₂SO₄

3. 0.01 M NaNO₂<0.01 M NaCl<0.01 M H₂S<0.01 M H₂SO₄

4. 0.01 M H₂S<0.01 M NaNO₂<0.01 M NaCl<0.01 M H₂SO₄

If the pressure of N₂ and H₂ mixture in a closed apparatus is 100 atm and 20% of the mixture then reacts, the pressure at  the same temperature would be:

1. 100                   

2. 90

3. 85                     

4. 80

The following reactions are known to occur in the body,

    CO₂ + H₂O$\rightleftharpoons$H₂CO₃$\rightleftharpoons$H⁺ + HCO₃^-                 

If CO₂ escapes from the system, then:

1. pH will decrease

2. hydrogen ion concentration will diminish

3. H₂CO₃ concentration will be unaltered

4. the forward reaction will be promoted

Which salt undergoes hydrolysis?

1. CH₃COONa                                     

2. KNO₃

3. NaCl                                               

4. K₂SO₄

If K₁ and K₂ are equilibrium constants for reactions (I) and (II) respectively for,

N₂ + O₂ $\rightleftharpoons$2NO           .....(i)

$\frac{1}{2}$N₂ + $\frac{1}{2}$O₂ $\rightleftharpoons$ NO     .....(ii)

Then:

1. K₂ =K₁                    

2. K₂ =$\sqrt{K_1}$

3. K₁ =2K₂                    

4. K₁ = $\frac{1}{2}$K₂

According to Le-Chatelier's principle, adding heat to a solid $\rightleftharpoons$liquid equilibrium will cause the :

1. Temperature to increase

2. Temperature to decrease

3. Amount of liquid to decrease

4. Amount of solid to decrease

Ostwald's solution dilution law is applicable in the case of the solution of:

1. CH₃COOH                                     

2. NaCl

3. NaOH                                           

4. H₂SO₄

At 25$°$C, the dissociation constant of a base, BOH is 1.0 x 10^-12. The concentration of hydroxyl ions in 0.01 M aqueous solution of the base would be                                     

1. 2.0 x 10^-6 mol L^-1             

2. 1.0 x 10^-5 mol L^-1 

3. 1.0 x10^-6 mol  L^-1             

4. 1.0 x10^-7 mol L^-1 

The pK_a of acetylsalicylic acid (aspirin) is 3.5. The pH of gastric juice in the human stomach is about 2-3 and the pH in the small intestine is about 8. Aspirin will be:

1. Unionized in the small intestine and in the stomach

2. Completely ionized in the small intestine and in the stomach

3. Ionized in the stomach and almost unionized in the small intestine

4. Ionized in the small intestine and almost unionized in the stomach

What is [H⁺] in mol/L of a solution that is 0.20 M in CH₃COONa and 0.10 M in CH₃COOH?

(K_a for CH₃COOH = 1.8 x 10^-5)       

1. 3.5x10^-4           

2. 1.1x10^-5

3. 1.8x10^-5           

4. 9.0x10^-6