Match List I with List II.
List I List II
(Process) (Conditions)
A. Isothermal process I. No heat exchange
B. Isochoric process II. Carried out at constant temperature
C. Isobaric process III. Carried out at constant volume
D. Adiabatic process IV. Carried out at constant pressure
Choose the correct answer from the options given below :
1. \(\text { A-IV, B-II, C-III, D-I }\)
2. \(\text { A-I, B-II, C-III, D-IV }\)
3. \(\text { A-II, B-III, C-IV, D-I }\)
4. \(\text { A-IV, B-III, C-II, D-I }\)
Subtopic:  Thermodynamics' Properties and process |
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In which of the following processes entropy increases?
A. A liquid evaporates to vapour.
B. Temperature of a crystalline solid lowered from \(130~\text{K}\) to \(0~\text{K}.\)
C. \(2 \mathrm{NaHCO}_{3(\mathrm{~s})} \rightarrow \mathrm{Na}_2 \mathrm{CO}_{3(\mathrm{~s})}+\mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})}\)
D. \(\mathrm{Cl}_{2(\mathrm{~g})} \rightarrow 2 \mathrm{Cl}_{(\mathrm{g})}\)
Choose the correct answer from the options given below :
1. \(\text { A, B and D }\) 2. \(\text { A, C and D }\)
3. \(\text { C and D }\) 4. \(\text { A and C }\)
Subtopic:  Spontaneity & Entropy |
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The work done during reversible isothermal expansion of one mole of hydrogen gas at 25°C from pressure of 20 atmosphere to 10 atmosphere is :
( Given R = 2.0 cal K-1 mol-1)

1. -413.14 calories
2. 413.14 calories 
3. 100 calories
4. 0 calorie
 
Subtopic:  First Law of Thermodynamics |
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Enthalpy of combustion of carbon to carbon dioxide is \(-390.0~\text{kJ mol}^{-1}.\) The amount of heat released when \(35.0~\text{g}\) of \(\mathrm{CO_2}\) is formed from the reaction of carbon and dioxygen gas, is:

1. \(310~\text{kJ}\)
2. \(490~\text{kJ}\)
3. \(245~\text{kJ}\)
4. \(700~\text{kJ}\)
Subtopic:  Enthalpy & Internal energy |
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Choose the correct statement for the work done in the expansion and heat absorbed or released when 5 liters of an ideal gas at 10 atmospheric pressure isothermally expands into a vacuum until the volume is 15 liters:
1. Both the heat and work done will be greater than zero.
2. Heat absorbed will be less than zero and work done will be positive.
3. Work done will be zero and heat will also be zero.
4. Work done will be greater than zero and heat will remain zero.
Subtopic:  First Law of Thermodynamics |
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For an endothermic reaction:
A. \(q_p \)(heat at constant pressure) is negative.
B. \(\Delta _r H \) (enthalpy change of the reaction) is positive.
C. \(\Delta _r H \) is negative. 
D. \(q_p \) is positive.
Which of the following combinations is correct?

1. B and D 
2. C and D 
3. A and B 
4. A and C
Subtopic:  Thermodynamics' Properties and process |
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For the following reaction at 300K 
\(\mathrm{A}_2(\mathrm{~g})+3 \mathrm{~B}_2(\mathrm{~g}) \rightarrow 2 \mathrm{AB}_3(\mathrm{~g})\)
the enthalpy change is +15 kJ, then the internal energy change is:

1. 19.98 K J 
2. 200 J
3. 1999 J 
4. 1.9988 kJ
Subtopic:  Enthalpy & Internal energy |
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What is the correct relationship between changes in enthalpy and internal energy within the following options?
1. \(\Delta \mathrm{H}+\Delta \mathrm{U}=\Delta \mathrm{nR} \)
2. \(\Delta \mathrm{H}=\Delta \mathrm{U -\Delta n_gRT}\)
3. \(\Delta \mathrm{H}=\Delta \mathrm{U+\Delta n_gRT }\)
4. \(\Delta \mathrm{H} -\Delta \mathrm{U=-\Delta n_gRT}\)
Subtopic:  Enthalpy & Internal energy |
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Consider the following reaction:
\(\mathrm{2H_2(g) + O_2(g) \rightarrow 2H_2O(g) \Delta_rH^\circ = -483.64 kJ. }\)
What is the enthalpy change for the decomposition of one mole of water?
1. 120.9 kJ 2. 241.82 kJ
3. 18 kJ 4. 100 kJ
Subtopic:  Thermochemistry |
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Which p-V curve among the following depicts the highest amount of work done?
 
1. 2.
3. 4.
Subtopic:  2nd & 3rd Law of Thermodynamics |
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