The boiling point of 0.2 mol kg^–1 solution of X in water is greater than the equimolal solution of Y in water. The correct statement in this case is:

The electrolyte having the same value of Van't Hoff factor (i) as that of Al₂(SO₄)₃  (if all are 100% ionized) is:

1. K₂SO₄
2. K₃[Fe(CN)₆]
3. Al(NO₃)₃
4. K₄[Fe(CN)₆]

The largest freezing point depression among the following 0.10 m solutions is shown by:

p_A and p_B are the vapour pressure of pure liquid components, A and B, respectively of an ideal binary solution.
If X_A represents the mole fraction of component A, the total pressure of the solution will be:

1. p_A + X_A (p_B-p_A)
2. p_A + X_A (p_A-p_B)
3. p_B + X_A (p_B-p_A)
4. p_B + X_A (p_A-p_B)

Vapour pressure of chloroform \(\mathrm{(CHCl_3)}\) and dichloromethane \(\mathrm{(CH_2Cl_2)}\) at $25°C$ are 200 mmHg and 41.5 mmHg respectively. Vapour pressure of the solution was obtained by mixing 25.5 g of \(\mathrm{(CHCl_3)}\) and 40 g of \(\mathrm{(CH_2Cl_2)}\) at the same temperature will be: (Molecular mass of \(\mathrm{(CHCl_3)}\) = 119.5 u and molecular mass of \(\mathrm{(CH_2Cl_2)}\) = 85 u)

The freezing point depression constant for water is 1.86 ^oC m^-1. If 5.00 g Na₂SO₄ is dissolved in 45.0 g H₂O, the freezing point is changed by -3.82 ^oC. The Van’t Hoff factor for Na₂SO₄ is:

The van’t Hoff factor, i, for a compound that undergoes
dissociation and association in a solvent is, respectively:

1. Less than one and less than one.
2. Greater than one and less than one.
3. Greater than one and greater than one.
4. Less than one and greater than one.

A 0.1 molal aqueous solution of a weak acid (HA) is 30 % ionized. If K_f for water is 1.86 °C/m, the freezing point of the solution will be: