A sample of \(0.1\) g of water at \(100^{\circ}\mathrm{C}\)$$ and normal pressure (\(1.013 \times10^5\) N m^–2) requires \(54\) cal of heat energy to convert it into steam at \(100^{\circ}\mathrm{C}\)$$. If the volume of the steam produced is \(167.1\) cc, then the change in internal energy of the sample will be:
1. \(104.3\) J
2. \(208.7\) J
3. \(42.2\) J
4. \(84.5\) J

The volume \((V)\) of a monatomic gas varies with its temperature \((T),\) as shown in the graph. The ratio of work done by the gas to the heat absorbed by it when it undergoes a change from state \(A\) to state \(B\) will be:
             

The efficiency of an ideal heat engine (Carnot heat engine) working between the freezing point and boiling point of water is:
1. \(26.8\%\)
2. \(20\%\)
3. \(6.25\%\)
4. \(12.5\%\)

Thermodynamic processes are indicated in the following diagram: 
   
Match the following: 

A gas is compressed isothermally to half its initial volume. The same gas is compressed separately through an adiabatic process until its volume is again reduced to half. Then:

One mole of an ideal monatomic gas undergoes a process described by the equation \(PV^3=\text{constant}.\) The heat capacity of the gas during this process is:
1. \(\frac{3}{2}R\)
2. \(\frac{5}{2}R\)
3. \(2R\)
4. \(R\)

A gas is compressed isothermally to half its initial volume. The same gas is compressed separately through an adiabatic process until its volume is again reduced to half. Then,