List I (Complex) | List II (Type of isomerism) |
A. \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{NO}_2\right)\right] \mathrm{Cl}_2\) | I. Solvate isomerism |
B. \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Br}\) | II. Linkage isomerism |
C. \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Cr}(\mathrm{CN})_6\right]\) | III. Ionization isomerism |
D. \(\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3\) | IV. Coordination |
Statement I : | Both \(\left[\text{Co}\left(\text{NH}_3\right)_6\right]^{3+}\) and \(\left[\text{CoF}_6\right]^{3-}\) Complexes are octahedral but differ in their magnetic behaviour. |
Statement II : | \(\left[\text{Co}\left(\text{NH}_3\right)_6\right]^{3+}\) is diamagnetic whereas \(\left[\text{CoF}_6\right]^{3-}\) is paramagnetic. |
Statement I: | \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}\) is a homoleptic complex, whereas \([Co(NH_3)_4 Cl_2]^+\) is a heteroleptic complex. |
Statement II: | Complex \([Co(NH_3)_6]^{3+}\) has only one kind of ligands but \([Co(NH_3)_4 Cl_2]^+\) has more than one kind of ligand |
List -I (Complex ion) |
List -II (Hybridisation) |
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A. | \([\mathrm{Ni}(\mathrm{CN})_4]^{2-}\) | I. | \(s p^3 \) |
B. | \(\mathrm{[CoF_6}]^{3-}\) | II. | \( d^2sp^3 \) |
C. | \([\mathrm{Co}(\mathrm{C}_2 \mathrm{O}_4)_3 ]^{3-}\) | III. | \(s p^3d^2\) |
D. | \(\left(\mathrm{NiCl}_4\right)^{2-}\) | IV. | \(dsp^2\) |
1. | Hexadentate ligand | 2. | Ambidentate ligand |
3. | Monodentate ligand | 4. | Bidentate ligand |
1. | \(\mathrm{C_2O^{2-}_4}\) | 2. | \(\mathrm{SCN}^-\) |
3. | \(\mathrm{NO^{-}_2}\) | 4. | \(\mathrm{CN}^-\) |