Which one of the following reactions does not come under hydrolysis type reaction?
1. \(\mathrm{S i C l_{4 \left(\right. l \left.\right)} + 2 H_{2} O_{\left(\right. l \left.\right)} \rightarrow S i O_{2 \left(\right. s \left.\right)} + 4 H C l_{\left(\right. a q \left.\right)}}\)
2. \(\mathrm{L i_{3} N_{\left(\right. s \left.\right)} + 2 H_{2} O_{\left(\right. l \left.\right)} \rightarrow N H_{3 \left(\right. g \left.\right)} + 3 L i O H_{\left(\right. a q \left.\right)}}\)
3. \(\mathrm{2 F_{2 \left(\right. g \left.\right)} + 2 H_{2} O_{\left(\right. l \left.\right)} \rightarrow 4 H F_{\left(\right. a q \left.\right)} + O_{2 \left(\right. g \left.\right)}}\)
4. \(\mathrm{P_{4} O_{10 \left(\right. s \left.\right)} + 6 H_{2} O_{\left(\right. l \left.\right)} \rightarrow 4 H_{3} P O_{4 \left(\right. a q \left.\right)}}\)
Statement I: | Acid strength increases in the order given as HF < HCl < HBr < HI. |
Statement II: | As the size of the elements F, Cl, Br, I increases down the group, the bond strength of HF, HCI, HBr, and HI decreases and so the acid strength increases. |
1. | Statement I is correct and Statement II is incorrect | |
2. |
|
|
3. | Both Statement I and Statement II are correct. | |
4. | Both Statement I and Statement II are incorrect. |
Choose the incorrect statement among the following regarding noble gases:
1. | Noble gases have weak dispersion forces. |
2. | Noble gases have large positive values of electron gain enthalpy. |
3. | Noble gases are sparingly soluble in water. |
4. | Noble gases have very high melting and boiling points. |
In which one of the following arrangements the given sequence is not strictly according to the properties indicated against it?
1. | NH3 < PH3 < AsH3 < SbH3 | Increasing acidic character |
2. | CO2 < SiO2 < SnO2 < PbO2 | Increasing oxidizing power |
3. | HF < HCl < HBr < HI | Increasing acidic strength |
4. | H2O < H2S < H2Se < H2Te | Increasing pKa values |
A compound 'X' upon reaction with produces a colorless gas 'Y' with rotton fish smell. Gas 'Y' is absorbed in a solution of to give as one of the products. Predict the compound 'X'
1.
2.
3.
4.
Compound of sulphur that has linkage among the following is:
1.
2.
3.
4.
Assertion (A): | ICl is more reactive than I₂. |
Reason (R): | I-Cl bond is weaker than I-I bond. |
1. | (A) is False but (R) is True. |
2. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
3. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
4. | (A) is True but (R) is False. |
Statement I: | The boiling points of the following hydrides of group 16 elements increase in the order \(\mathrm{H}_{2} \mathrm{O}<\mathrm{H}_{2} \mathrm{~S}<\mathrm{H}_{2} \mathrm{Se}<\mathrm{H}_{2} \mathrm{Te} \) |
Statement II: | The boiling points of these hydrides increase with the increase in molar mass. |
The correct order for boiling points of the following compounds is:
1. | AsH3 > PH3 > NH3 > SbH3 > BiH3 |
2. | BiH3 > SbH3 > NH3 > AsH3 > PH3 |
3. | NH3 > PH3 > AsH3 > SbH3 > BiH3 |
4. | PH3 > NH3 > AsH3 > SbH3 > BiH3 |
Chlorine shows the bleaching action in the presence of moisture due to the formation of
1. HOCl
2. HOClO
3. H2O2
4. O