Statement I : | The boiling point of three isomeric pentanes follows the order \(\small\text { n-Pentane }>\text { Isopentane }>\text { Neopentane }\) |
Statement II : | When branching increases, the molecule attains the shape of sphere. This results in smaller surface area for contact, due to which the intermolecular forces between the spherical molecules are weak, thereby lowering the boiling point. |
Determine the IUPAC name of the compound with the molecular formula C₆H₁₄ that contains two tertiary carbon atoms.
1. 2-Methyl pentane
2. 2, 3-Dimethylbutane
3. 2, 2-Dimethylbutane
4. n-Hexane
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List-I (Reactions) |
List-II (Products) |
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I. | \(\small\mathrm{{\left({CH}_3\right)_2 {C}={O}+{CO}_2+\mathrm{H}_2 {O} }}\) |
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IV. | \(\left(\mathrm{CH}_3\right)_3 \mathrm{C}-\mathrm{OH} \) |
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Statement I : | Propene on treatment with diborane gives an addition product with the formula \((CH_3)_2-CH)_3 -B \) |
Statement II : | Oxidation of \((CH_3)_2-CH)_3 -B\) with hydrogen peroxide in presence of \(NaOH \) gives propan-2-ol. |
1. | Acidic potassium permanganate solution |
2. | Acidic potassium dichromate solution |
3. | Cold, dilute, aqueous solution of potassium permanganate |
4. | Hot, concentrated solution of potassium permanganate |
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