Phthalic acid on heating with SOCl2 gives:
1. | Phthalic anhydride | 2. | Phthalamide |
3. | Phthaloyl chloride | 4. | None of the above |
An organic compound (A) contains 69.77% carbon, 11.63% hydrogen, and rest oxygen. The molecular mass of the compound is 86. It does not reduce Tollens’ reagent but forms an addition compound with sodium hydrogen sulphite and gives a positive iodoform test. On vigorous oxidation, it gives ethanoic and propanoic acid. Compound A would be:
1. Pentan-2-one
2. Butanone
3. 3-Methylbutanone
4. Propan-2-ol
The correct sequence of increasing orders of reactivity in nucleophilic addition reaction is:
1. Butanone < Propanone < Propanal < Ethanal
2. Butanone > Propanone > Propanal > Ethanal
3. Butanone < Propanal < Propanone < Ethanal
4. Propanal < Propanone < Ethanal < Butanone
Cannizzaro’s reaction is not given by:
1. | 2. | ||
3. | HCHO | 4. | CH3CHO |
The compound below is treated with a concentrated aqueous KOH solution. The products obtained are:
1. | |
2. | |
3. | |
4. |
What is the most suitable reagent for the below mentioned conversion?
\(\mathrm{CH_{3} — CH = CH — CH_{2} — \overset{\Large{O} \\~ ||}{C}—CH_{3} \rightarrow}\)
\(\mathrm{CH_{3} — CH = CH — CH_{2} — \overset{\Large{O} \\~ ||}{C}—OH}\)
1. Tollens' reagent
2. Benzoyl peroxide
3. \(\mathrm I_{2}\) and NaOH solution
4. Sn and NaOH solution
The conversions can be used for Clemmensen reduction are:
a. Benzaldehyde into benzyl alcohol.
b. Cyclohexanone into cyclohexane.
c. Benzoyl chloride into benzaldehyde.
d. Benzophenone into diphenyl methane.
1. | a and b | 2. | b and c |
3. | c and d | 4. | b and d |
Match the common names given in Column I with the IUPAC names given in Column II.
Column l (Common names) |
Column ll (IUPAC names) |
A. Cinnamaldehyde | 1. Pentanal |
B. Acetophenone | 2. Prop-2-enal |
C. Valeraldehyde | 3. 1-Phenylethanone |
D. Acrolein | 4. 3-Phenylprop-2-en-al |
Codes:
A | B | C | D | |
1. | 2 | 3 | 4 | 1 |
2. | 3 | 1 | 4 | 2 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 3 | 1 | 2 |
Match the acids given in Column I with their correct IUPAC names given in Column II and mark the appropriate option:
Column l (Acids) |
Column ll (IUPAC names) |
A. Phthalic acid | 1. Hexane-1,6-dioic acid |
B. Glutaric acid | 2. Benzene-1,2-dicarboxylic acid |
C. Succinic acid | 3. Pentane-1,5-dioic acid |
D. Adipic acid | 4. Butane-1,4-dioic acid |
Codes:
A | B | C | D | |
1. | 2 | 3 | 4 | 1 |
2. | 3 | 1 | 4 | 2 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 3 | 2 | 1 |
Match the reactions given in Column I with the suitable reagents given in Column II.
Column l (Reactions) |
Column ll (Reagents) |
A. Benzophenone → Diphenylmethane | 1. LiAlH4 |
B. Benzaldehyde → 1-Phenylethanol | 2. DlBAL-H |
C. Cyclohexanone → Cyclohexanol | 3. Zn(Hg)/Conc.HCl |
D. Phenyl benzoate → Benzaldehyde | 4. CH3MgBr |
Codes:
A | B | C | D | |
1. | 2 | 3 | 4 | 1 |
2. | 3 | 4 | 1 | 2 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 3 | 2 | 1 |