The most stable carbocation among the following is-
1. \(({CH_3})_3C\overset{+}{C}H_2\)
2. \(({CH_3})_3\overset{+}{C}\)
3. \({CH_3}CH_2\overset{+}{C}H_2\)
4. \(({CH_3})\overset{+}{C}HCH_2CH_3\)
is more stable than because :
1. | NO2 shows +I effect |
2. | NO2 shows -I effect |
3. | NO2 decreases the positive charge on the compound |
4. | Ethyl group increases positive charge on the compound |
An electrophile among the following is :
1. | \(\mathrm{OH}^-\) | 2. | \(\mathrm{NC}^-\) |
3. | \(R_3C^-\) | 4. | Carbonyl group |
The most stable carboxylate ion among the following is-
1.
2.
3.
4.
The correct representation involving heterolytic fission of among the following is:
1. | |
2. | |
3. | |
4. |
The addition of HCl to an alkene proceeds in two steps. The first step is the attack of H+ ion on the double bond portion. The same can be shown as-
1. | 2. | ||
3. | 4. | All of these are possible |
Match the type of mixture of compounds in Column I with the technique of separation/purification given in column II.
Column I | Column II |
A. Two solids which have different solubilities in a solvent and which do not undergo a reaction when dissolved in it | 1. Steam distillation |
B. Liquid that decomposes at its boiling point | 2. Fractional distillation |
C. Steam volatile liquid | 3. Crystallisation |
D. Two liquids that have boiling points close to each other | 4. Distillation under reduced pressure |
Codes:
A | B | C | D | |
1. | 3 | 4 | 1 | 2 |
2. | 1 | 2 | 3 | 4 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 1 | 3 | 2 |
Match Column I with Column II.
Column I | Column II |
A. Dumas method | 1. AgNO3 |
B. Kjeldahl’s method | 2. Silica gel |
C. Carius method | 3. Nitrogen gel |
D. Chromatography | 4. Ammonium sulphate |
Codes:
A | B | C | D | |
1. | 3 | 4 | 1 | 2 |
2. | 1 | 2 | 3 | 4 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 1 | 3 | 2 |
Metallic sodium is fused with organic compounds for testing nitrogen, sulphur, and halogens. The correct reason behind this is:
1. | To convert all compounds to their ionic form. |
2. | Sodium reduces the compounds. |
3. | Sodium converts all compounds in their covalent form. |
4. | None of the above. |