The correct IUPAC name of the following compound is:

 

1. 5-Oxohexanoic
2. 2-Oxohexan-5-oic
3. 5-Carboxylpentan-2-one
4. Hexan-2-on-6-oic

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
 88%
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Match the items in column I with items in column II.
Column I
Reactions
Column II
Reagents
i. Hexan-1-ol to hexanal a. (Diisobutyl)aluminiumhydride (DIBAL-H)
ii. Ethanenitrile to ethanal b. Chromyl chloride in the presence of CS2
iii. p-Fluorotoluene to  p-fluorobenzaldehyde c. PCC 
(Pyridinium chlorochromate)


1. i=c; ii=a; iii=b
2. i=b; ii=c; iii=a
3. i=c; ii=b; iii=a
4. i=a; ii=b; iii=c

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
 84%
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Consider the following reaction.

Benzyl alcohol + HBr → X   \(\xrightarrow[]{KCN}\)  Y \(\xrightarrow[]{H^{+}, \ H_{2}O}\) Z
The product Z is as follows:

1. 2-Phenylethanoic acid
2. 2-Phenylcarboxylic acid
3. 1-Phenylethanoic acid
4. None of the above
Subtopic:  Carboxylic Acids: Preparation & Properties |
 62%
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The conversion of 4-Methylacetophenone to benzene-1,4-dicarboxylic acid can be achieved by-

1. i. HCN;  ii. H+/H2O
2. ii. LiAlH4; ii. H+/H2O
3. i. KMnO4/KOH;  ii. dil. H2SO4
4. i. CH3MgBr; ii. H+/H2O
Subtopic:  Carboxylic Acids: Preparation & Properties |
 79%
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Consider the following reaction.
 
The structure of A is:
1.
2.
3.
4. None of the above
Subtopic:  Carboxylic Acids: Preparation & Properties |
 65%
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Butanal → Butanoic acid

The best reagent for the above transformation is:

1. Tollen's reagent
2. KMnO4
3. K2Cr2O7
4. All of the above
Subtopic:  Carboxylic Acids: Preparation & Properties |
 82%
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Consider the given statements:

Statement I: The conversion of but-2-ene to ethanal can be obtained by reductive ozonolysis. 
Statement II: The conversion of allyl alcohol to propenal is a reduction reaction and can be achieved using the PCC reagent.
 
1. Statement I is correct; Statement II is correct.
2. Statement I is correct; Statement II is incorrect.
3. Statement I is incorrect; Statement II is correct.
4. Statement I is incorrect; Statement II is incorrect.
 
Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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