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Q. No.Thermodynamics is not concerned about which of the following?
| 1. | Energy changes involved in a chemical reaction. |
| 2. | The extent to which a chemical reaction proceeds. |
| 3. | The rate at which a reaction proceeds. |
| 4. | The feasibility of a chemical reaction. |
Which among the following statements about open, closed, and isolated systems is correct?
| 1. | The presence of reacting species in a covered beaker represents an open system. |
| 2. | In a closed system, there is an exchange of both energy and matter between the system and its surroundings. |
| 3. | A system containing reactants in a closed vessel made of copper is an example of a closed system. |
| 4. | A system containing reactants in a thermos flask or any other closed, insulated vessel is an example of a closed system. |
| Assertion (A): | Variables like P, V, and T are called state functions. |
| Reason (R): |
Their values depend solely on the system's state, and not on how it is reached. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
| List-I (Process) | List-II (Conditions) | ||
| A. | Isothermal process | I. | No heat exchange |
| B. | Isochoric process | II. | Carried out at constant temperature |
| C. | Isobaric process | III. | Carried out at constant volume |
| D. | Adiabatic process | IV. | Carried out at constant pressure |
| 1. | \(\text { A-IV, B-II, C-III, D-I }\) | 2. | \(\text { A-I, B-II, C-III, D-IV }\) |
| 3. | \(\text { A-II, B-III, C-IV, D-I }\) | 4. | \(\text { A-IV, B-III, C-II, D-I }\) |
In an adiabatic process, no transfer of heat takes place between the system and its surroundings. The correct option for free expansion of an ideal gas under adiabatic condition from the following is:
1.
2.
3.
4.
A. \(q_p \) (heat at constant pressure) is negative.
B. \(\Delta _r H \) (enthalpy change of the reaction) is positive.
C. \(\Delta _r H \) is negative.
D. \(q_p \) is positive.
Which of the following combinations is correct?
| 1. | B and D | 2. | C and D |
| 3. | A and B | 4. | A and C |
What is a necessary condition for an adiabatic process to occur?
1. ∆T = 0
2. ∆P = 0
3. q = 0
4. w = 0
The enthalpy of formation of all elements in their standard state is-
| 1. | Unity | 2. | Zero |
| 3. | Less than zero | 4. | Different for each element |
The amount of heat needed to raise the temperature of 60.0 g of aluminium from 35°C to 55°C would be:
(Molar heat capacity of Al is \(24\) \(J\) \(\text{mol}^{- 1}\) \(K^{- 1}\))
| 1. | \(1 . 07\) \(J\) | 2. | \(1 . 07\) \(kJ\) |
| 3. | \(106 . 7\) \(kJ\) | 4. | \(100 . 7\) \(kJ\) |
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