Match the terms in List I with their corresponding descriptions in List II:
List I (Term) | List II (Description) | ||
A. | Adiabatic process | i. | At constant temperature |
B. | Isolated system | ii. | No transfer of heat |
C. | Isothermal change | iii. | Heat |
D. | Path function | iv. | No exchange of energy and matter |
Codes:
A | B | C | D | |
1. | ii | iv | i | iii |
2. | iii | iv | i | ii |
3. | iv | iii | i | ii |
4. | iv | ii | i | iii |
Column-I (Process) |
Column-II
(Expression)
|
||
a. | No heat is absorbed by the system from the surroundings, but work (w) is done on the system. | i. | ∆U = q – w, closed system. |
b. | No work is done on the system, but q amount of heat is taken out from the system and given to the surroundings. | ii. | ΔU=Wad, for an adiabatic wall. |
c. | w amount of work is done by the system and q amount of heat is supplied to the system. | iii. | ∆U = –q, thermally conducting walls. |
1. | a = i; b = ii; c = iii | 2. | a = ii; b = i; c = iii |
3. | a = ii; b = iii; c = i | 4. | a = iii; b = ii; c = i |
An ideal gas is allowed to expand form 1 L to 10 L against a constant external pressure of 1 bar. The work done in kJ is:
1. +10.0
2. – 9.0
3. – 2.0
4. –0.9
The work done during the expansion of a gas from a volume of 4 dm3 to 6 dm3 against a constant external pressure of 3 atm is:
1. –608 J
2. +304 J
3. –304 J
4. –6.00 J
An ideal gas expands isothermally from 10-3m3 to 10-2 m310−3m3 to 10−2 m3 at 300 K against a constant pressure of 105 Nm-2105 Nm−2. The work done by the gas is:
1. | +270 kJ | 2. | –900 J |
3. | +900 kJ | 4. | –900 kJ |
The pressure-volume work for an ideal gas can be calculated by using the expression W=∫VfVipexdVW=∫VfVipexdV.
The work can also be calculated from the pV-plot by using the area under the curve within the specified limits.
An ideal gas is compressed (a) reversibly or (b) irreversibly from volume ViVi to VfVf.
The correct option is:
1. W (reversible)=W (irreversible)W (reversible)=W (irreversible)
2. W (reversible)<W (irreversible)W (reversible)<W(irreversible)
3. W (reversible)>W (irreversible)W (reversible)>W (irreversible)
4. W (reversible)=W (irreversible)+pex.∆VW (reversible)=W (irreversible)+pex.ΔV
1. | 2.29×1042.29×104 | 2. | 2.29×10−42.29×10−4 |
3. | −2.29×104−2.29×104 | 4. | −2.29×10−4−2.29×10−4 |