For the given cell, Mg | Mg2+ || Cu2+ | Cu

a.  Mg acts as cathode

b.  Cu acts as cathode

c.  The cell reaction is   \(Mg + Cu^{2+} \rightarrow Mg^{2+} + Cu\)

d.  Cu is the oxidising agent

The correct choice among the given is - 

1. (a, b) 2. (b, c)
3. (c, d) 4. (a, d)
Subtopic:  Electrolytic & Electrochemical Cell | Nernst Equation |
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Given:
\(E^\circ_{Fe/Fe^{2+}}=0.44~V~\text{and}~E^\circ_{Sn/Sn^{2+}}=0.14~V. \)
The \(E^\circ \) for the cell: \(\mathrm{Fe}(\mathrm{~s})+\mathrm{Sn}^{2+}(a q) \rightarrow \mathrm{Fe}^{2+}(a q)+\mathrm{Sn}(\mathrm{~s})\) will be:
1. 0.58 V 2. –0.30 V
3. 0.30 V 4. –0.58 V
Subtopic:  Nernst Equation |
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The electrode potential for Mg electrode varies according to the equation

\(E_{Mg^{2+}/Mg}\ = \ E_{Mg^{2+}/Mg}^{o} \ - \ \frac{0.059}{2}log\frac{1}{[Mg^{2+}]}\) 

The graph of EMg2+ / Mg vs log [Mg2+] among the following is:

1.    2.  
3.    4.  
Subtopic:  Nernst Equation |
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Find the emf of the cell in which the following reaction takes place at 298 K:
\(\mathrm{Ni}(\mathrm{s})+2 \mathrm{Ag}^{+}(0.001 \mathrm{M}) \rightarrow \mathrm{Ni}^{2+}(0.001 \mathrm{M})+2 \mathrm{Ag}(\mathrm{s}) \)
\( \small{\text { (Given that } \mathrm{E}_{\text {cell }}^{\circ}=10.5 \mathrm{~V}, \frac{2.303 \mathrm{RT}}{\mathrm{F}}=0.059 \text { at } \ 298 \mathrm{~K})} \)
1. 1.05 V
2. 1.0385 V 
3. 1.385 V
4. 0.9615 V 

Subtopic:  Nernst Equation |
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The value of Ecell in the reaction below will be:

\(\small{Pt(s)|Br^{-}(0.010 \ M)|Br_{2}(l) \ ||H^{+}(0.030 \ M)|H_{2}(g)(1 \ bar)|Pt(s)}\)

\(E_{Br^{-}/Br_{2}}^{o} \ = \ -1.09 \ V\)

1. +1.298 V

2. –1.398 V

3. –1.298 V

4. –1.198 V
Subtopic:  Nernst Equation |
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The rusting of iron takes place as follows:
\(\begin{aligned} & 2 \mathrm{H}^{+}+2 \mathrm{e}^{-}+1 / 2 \mathrm{O}_2 \longrightarrow \mathrm{H}_2 \mathrm{O}(1) ; E^{\circ}=+1.23 \mathrm{~V} \\ & \mathrm{Fe}^{2+}+2 \mathrm{e}^{-} \longrightarrow \mathrm{Fe}(\mathrm{s}) ; E^{\circ}=-0.44 \mathrm{~V} \end{aligned}\)

Calculate \(\Delta G^o\) for the net process:
1. –322 kJ mol–1 2. –161 kJ mol–1
3. –152 kJ mol–1 4. –76 kJ mol1
Subtopic:  Nernst Equation | Corrosion |
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Mg(s) + 2Ag+(0.0001M)  Mg2+(0.130M) + 2Ag(s)

If  EƟ(cell) for the above mentioned cell is 3.17 V, then E(cell) value will be-

(log 13=1.1)

1. 2.87 V
2. 3.08 V
3. 2.96 V
4. 2.68 V

Subtopic:  Nernst Equation |
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The emf of the cell in which the following reaction takes place is:

Ni(s)+2Ag+(0.002 M) →Ni2+(0.160 M) + 2Ag(s)
( Given that \(E_{cell}^{o}\)= 1.05 V)

1. Ecell= 9.14 V
2. Ecell= 0.0914 V
3. Ecell= 0.00914 V
4. Ecell= 0.914 V

Subtopic:  Nernst Equation |
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Ecello= 1.1 V for Daniel cell. Which of the following expressions are correct descriptions of the state of equilibrium in this cell?

(a) 1.1 = KC

(b) 2.303RT2FlogKC=1.1

(c) logKC=2.20.059

(d) log KC = 1.1

The correct choice among the given is -

1. (a, b)

2. (b, c)

3. (c, d)

4. (a, d)

Subtopic:  Nernst Equation |
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Mg(s) | Mg2+(0.001M) || Cu2+(0.0001 M) | Cu(s)

EMg2+/Mgo=-2.36 V; ECu2+/Cuo=0.34V

The value of Ecell  for the above reaction is -

1. 3.46 V  2. 3.15 V
3. 2.67 V 4. 1.24 V
Subtopic:  Nernst Equation |
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