Q. No.| 1. | Inversion of cane sugar |
| 2. | Radioactive decay |
| 3. | Hydrogenation of ethene |
| 4. | Decomposition of gaseous ammonia on a hot platinum surface at high pressure |
Consider the graph given in the figure. Which of the following options does not show an instantaneous rate of reaction in the 40s?
1. \({V_5 -V_2 \over 50-30}\)
2. \({V_4 -V_2 \over 50-30}\)
3. \({V_3 -V_2 \over 40-30}\)
4. \({V_3 -V_1 \over 40-20}\)
Match the items in Column I with Column II:
| Column I | Column II |
| A. Diamond to graphite conversion | 1. Short interval of time |
| B. Instantaneous rate | 2. Ordinarily rate of conversion is imperceptible |
| C. Average rate | 3. Long duration of time |
Codes:
| A | B | C | |
| 1. | 2 | 1 | 3 |
| 2. | 1 | 2 | 3 |
| 3. | 3 | 2 | 1 |
| 4. | 1 | 3 | 2 |
A graph of volume of hydrogen released vs time for the reaction between zinc and dil. HCl is given in the graph below.
The correct statement among the following based on the graph given above is:
The correct expression for the rate of reaction given below is:
\(5 \mathrm{Br}^{-}(\mathrm{aq})+\mathrm{BrO}_3^{-}(\mathrm{aq})+6 \mathrm{H}^{+}(\mathrm{aq}) \rightarrow 3 \mathrm{Br}_2(\mathrm{aq})+3 \mathrm{H}_2 \mathrm{O}(\mathrm{l})\)
| 1. | \(\frac{\Delta\left[B r^{-}\right]}{\Delta t}=5 \frac{\Delta\left[H^{+}\right]}{\Delta t} \) | 2. | \(\frac{\Delta\left[\mathrm{Br}^{-}\right]}{\Delta t}=\frac{6}{5} \frac{\Delta\left[\mathrm{H}^{+}\right]}{\Delta t} \) |
| 3. | \(\frac{\Delta[\mathrm{Br^-}]}{\Delta t}=\frac{5}{6} \frac{\Delta\left[\mathrm{H}^{+}\right]}{\Delta t} \) | 4. | \(\frac{\Delta\left[\mathrm{Br}^{-}\right]}{\Delta t}=6 \frac{\Delta\left[\mathrm{H}^{+}\right]}{\Delta t}\) |
\(2 \mathrm{HI}_{(g)} \rightarrow \mathrm{H}_{2(g)}+\mathrm{I}_{2(g)}\)
1. \(\dfrac{-\Delta[\mathrm{H}I]}{\Delta t}=\dfrac{2 \Delta\left[\mathrm{H}_2\right]}{\Delta t}\)
2. \(\dfrac{-\Delta[\mathrm{HI}]}{\Delta t}=\dfrac{4\Delta\left[\mathrm{I}_2\right]}{\Delta t}\)
3. \(\dfrac{-\Delta[\mathrm{HI}]}{\Delta t}=\dfrac{4 \Delta\left[\mathrm{H}_2\right]}{\Delta t}\)
4. \( \dfrac{-\Delta[\mathrm{H}]}{\Delta t}=\dfrac{\Delta\left[\mathrm{H}_2\right]}{\Delta t}\)
The average rate of appearance of B is given by \(\Delta [B] \over \Delta t\).
The correct relation between the average rate of appearance of B with the average rate of disappearance of A is:
| 1. | \(-\Delta [A] \over \Delta t\) | 2. | \(-3\Delta [A] \over 2\Delta t\) |
| 3. | \(-2\Delta [A] \over 3\Delta t\) | 4. | \(\Delta [A] \over \Delta t\) |
True statement among the following is:
| 1. | The rate of a reaction decreases with the passage of time as the concentration of reactants decreases. |
| 2. | The rate of a reaction is the same at any time during the reaction. |
| 3. | The rate of a reaction is independent of temperature change. |
| 4. | The rate of a reaction decreases with an increase in the concentration of the reactants. |
rate of formation of C is 6 × 10–2 mol L–1 s–1 and rate of disappearance of A is 4 × 10–2 mol L–1 s–1. The rate of reaction and amount of B consumed in interval of 10 seconds, respectively will be:
| 1. | 1 × 10–2 mol L–1 s–1 and 30 × 10–2 mol L–1 |
| 2. | 10 × 10–2 mol L–1 s–1 and 10 × 10–2 mol L–1 |
| 3. | 1 × 10–2 mol L–1 s–1 and 10 × 10–2 mol L–1 |
| 4. | 10 × 10–2 mol L–1 s–1 and 30 × 10–2 mol L–1 |
The decomposition of N2O5 in CCl4 at 318K has been studied by monitoring the concentration of N2O5 in the solution. Initially, the concentration of N2O5 is 2.33 mol L–1 and after 184 minutes, it is reduced to 2.08 mol L–1. The reaction takes place according to the equation
2 N2O5 (g) → 4 NO2 (g) + O2 (g)
The rate of production of NO2 during this period is-
1. 5.72 × 10–3 mol L–1 min–1
2. 2.72 × 10–3 mol L–1 min–1
3. 1.72 × 10–5 mol L–1 min–1
4. 6.72 × 10–4 mol L–1 min–1
© 2024 GoodEd Technologies Pvt. Ltd.