| Assertion (A): | In presence of NaBH4, \(~~~~~~~~~~~~~~~~~~~~~~~~~O\\ ~~~~~~~~~~~~~~~~~~~~~~~~~\|\\ CH_2=CH-C-H\) is reduced to give \(CH_3-CH_2-CH_2OH.\) |
| Reason (R): | NaBH4 reduces conjugated double bonds also. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
| Assertion (A): | Benzaldehyde is less reactive than acetaldehyde towards nucleophiles. |
| Reason (R): | Carbonyl carbon in benzaldehyde has less positive charge than that of carbonyl carbon in acetaldehyde due to resonance. |
| 1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
| 3. | (A) is true but (R) is false. |
| 4. | Both (A) and (R) are false. |
| Assertion (A): | Formic acid can be oxidized to carbonic acid. |
| Reason (R): | Formic acid does not give brisk effervescence with NaHCO3. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
| Assertion (A): | Aldehydes and ketones give nucleophilic addition reaction but acyl derivatives give nucleophilic substitution reaction. |
| Reason (R): | Aldehydes and ketones contain stronger bases and poor leaving groups in comparison to acyl derivatives. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
| List-I (Chemical Composition) |
List-II (Reagent) |
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| (A) | Benzenesulphonyl chloride | (I) | Tollen's reagent |
| (B) | Anhydrous ZnCl2 + Conc. HCl | (II) | Fehling A solution |
| (C) | Ammoniacal silver nitrate | (III) | Hinsberg's reagent |
| (D) | Aqueous CuSO4 solution | (IV) | Lucas reagent |
| (A) | (B) | (C) | (D) | |
| 1. | (IV) | (III) | (I) | (II) |
| 2. | (III) | (IV) | (I) | (II) |
| 3. | (III) | (IV) | (II) | (I) |
| 4. | (I) | (II) | (IV) | (III) |
| Assertion (A): | Acetic acid is more acidic than phenol. |
| Reason (R): | Acetate ion is more stable than phenoxide ion. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
| A. | ![]() |
| B. | ![]() |
| C. | ![]() |
| D. | ![]() |