The correct statement for a reversible process in a state of equilibrium is:
1. G = – 2.30RT log K
2. G = 2.30RT log K
3. Go = – 2.30RT log K
4. Go = 2.30RT log K

Subtopic:  Gibbs Energy Change |
 81%
Level 1: 80%+
NEET - 2015
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What is the value of \(\mathrm{K_{sp}}\) of \(\mathrm {Ag_2CO_3 (s) }\) in water at 25º C for the following reaction; 
\(\mathrm{Ag_2 CO_3 (s) \rightarrow 2Ag^+ (aq) + CO^{2-}_3 (aq)}\)

[Given: \(\text R = 8.314 \text J\text K^{–1} \text {mol}^{–1}\) \(\Delta \text G^\circ=+63.3~\text{kJ}\) ]

1. \(3.2 \times 10^{26}\)
2. \(8.0 \times 10^{-12}\)
3. \(2.9 \times 10^{-3}\)
4. \(7.9 \times 10^{-2}\)
Subtopic:  Gibbs Energy Change |
 61%
Level 2: 60%+
AIPMT - 2014
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Given the following reaction:
\(4H(g)\)→  \(2 H_{2}\)\((g)\)
The enthalpy change for the reaction is -869.6 kJ. The dissociation energy of the H-H bond is:
1. -869.6 kJ
2. +434.8kJ
3. +217.4kJ
4. -434.8 kJ

Subtopic:  Enthalpy & Internal energy |
 67%
Level 2: 60%+
AIPMT - 2011
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Give the following bond energies:
H—H bond energy: 431.37 kJ mol-1 
C=C bond energy: 606.10 kJ mol-1 
C—C bond energy: 336.49 kJ mol-1 
C—H bond energy: 410.50 kJ mol-1 

Enthalpy for the following reaction will be:

1. 1523.6 kJ mol-1
2. -243.6 kJ mol-1
3. -120.0 kJ mol-1
4. 553.0 kJ mol-1
Subtopic:  Thermochemistry |
 76%
Level 2: 60%+
AIPMT - 2009
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The values of ΔH and ΔS for the given reaction are 170 kJ and 170 JK-1, respectively.
C(graphite) + CO2(g)→2CO(g) 
This reaction will be spontaneous at:

1. 710 K
2. 910 K
3. 1110 K
4. 510 K

Subtopic:  Gibbs Energy Change |
 88%
Level 1: 80%+
AIPMT - 2009
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The standard free energies of formation(in kJ/mol) at 298 K are -237.2, -394.4, and -8.2 for H2O(l), CO2(g), and pentane (g), respectively. The value of Ecell for the pentane-oxygen fuel cell is:

1. 1.968 V
2. 2.0968 V
3. 1.0968 V
4. 0.0968 V

Subtopic:  Gibbs Energy Change |
 52%
Level 3: 35%-60%
AIPMT - 2008
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The bond energy of H—H and Cl-Cl is 430 kJ
mol-1 and 240 kJ mol-1 respectively and ΔHf for HCl is -90 kJ mol-1. The bond enthalpy of HCl is:

1. 290 kJ mol-1

2. 380 kJ mol-1

3. 425 kJ mol-1

4. 245 kJ mol-1

Subtopic:  Thermochemistry |
 63%
Level 2: 60%+
AIPMT - 2007
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Two moles of an ideal gas is heated at a constant pressure of one atmosphere from 27°C to 127°C. If Cv,m=20+10-2TJK-1mol-1, then q and U for the process are respectively:

1.  6362.8 J, 4700 J

2.  3037.2 J, 4700 J

3.  7062.8 J, 5400 J

4.  3181.4 J, 2350 J

Subtopic:  Cp & Cv |
Level 3: 35%-60%
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Calculate fH° (in kJ/mol) for Cr2O3 from the rG° and the S° values provided at 27°C

\(\begin{array}{ll} 4 C r(s)+3 O_2(g) \rightarrow 2 C r_2 O_3(s), \\ \Delta_r G^{\circ}=-2093.4 k J / m o l \\ S^{\circ}(\mathrm{J} / / \mathrm{K} \mathrm{~mol}): S^{\circ}(C r, s)=24, \\ S^{\circ}\left(O_2, g\right)=205, \quad S^{\circ}\left(C r_2 O_3, s\right)=81 \end{array}\)

1.  -2258.1 kJ/mol
2.  -1129.05 kJ/mol
3.  -964.35 kJ/mol
4.  None of the above

Subtopic:  Gibbs Energy Change |
Level 3: 35%-60%
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The standard heat of combustion of propane is –2220.1 kJ mol–1. The standard heat of vaporisation of liquid water is 44.0 kJ mol–1. The enthalpy change for the reaction is–

C3H8 (g) + 5O2 (g) 3CO2 (g) + 4H2O(g)

1. –2220.1 kJ 2. –2044.1 kJ
3. –2396.1 kJ 4. –2176.1 kJ
Subtopic:  Thermochemistry |
 50%
Level 3: 35%-60%
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