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Q. No.Incorrect match among the following is:
| 1. | Tetraamminediaquacobalt(III) chloride |
[Co(H2O)2(NH3)4]Cl3 |
| 2. | Ammine bromidochloridonitrito-N-platinate(II) |
[Pt(NH3)BrCl(NO2)]- |
| 3. | Dichloridobis (ethane−1,2−diamine) platinum(IV)nitrate |
[PtCl2(en)2](NO3)2 |
| 4. | Iron(III) hexacyanoferrate(II) | Fe2[Fe(CN)6]3 |
Subtopic: Introduction, Classification and Nomenclature |
57%
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Match the items given in column I with column II.
1. a-iv; b-iii; c-ii; d-i
2. a-iv; b-i; c-ii; d-iii
3. a-iii; b-i; c-iv; d-ii
4. a-ii; b-iv; c-i; d-iii
| Column I | Column II | ||
| a. | K3[Fe(C2O4)3] | i. | Diamminechlorido(methylamine) platinum(II) chloride |
| b. | [Co(NH3)5Cl]Cl2 | ii. | Potassium trioxalatoferrate(III) |
| c. | [Pt(NH3)2Cl(NH2CH3)]Cl | iii. | Potassium tetrachlorido palladate(II) |
| d. | K2[PdCl4] | iv. | Pentaamminechloridocobalt(III) chloride |
2. a-iv; b-i; c-ii; d-iii
3. a-iii; b-i; c-iv; d-ii
4. a-ii; b-iv; c-i; d-iii
Subtopic: Introduction, Classification and Nomenclature |
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The type(s) of isomerism exhibited by the K[Cr(H2O)2(C2O4)2] complexes is:
1. Geometrical isomerism
2. Optical isomerism
3. Linkage isomerism
4. Both 1 and 2
Subtopic: Isomerism in Coordination Compounds |
76%
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The relation between given pair of complexes is:
[Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl
1. Coordination isomers
2. Linkage isomers
3. Ionization isomers
4. Optical isomers
[Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl
1. Coordination isomers
2. Linkage isomers
3. Ionization isomers
4. Optical isomers
Subtopic: Isomerism in Coordination Compounds |
85%
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| Statement I: | [Ni(CN)4]2− structure is tetrahedral and diamagnetic in nature. |
| Statement II: | [NiCl4]2− structure is tetrahedral and diamagnetic in nature. |
1. Both Statement I and Statement II are true.
2. Statement I is true and Statement II is false.
3. Both Statement I and Statement II are false.
4. Statement I is false, Statement II is true.
Subtopic: VBT, CFT & their Limitations |
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Given below are two statements:
| Assertion (A): | [NiCl4]2− is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral. |
| Reason (R): | CO is a strong field ligand, thus pairing of electrons takes place in [Ni(CO)4]. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
Subtopic: VBT, CFT & their Limitations |
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Select the correct option based on statements below:
| I: | [Fe(H2O)6]3+ is strongly paramagnetic whereas [Fe(CN)6]3− is weakly paramagnetic. |
| II: | [Fe(H2O)6]3+ has 4 unpaired electrons while [Fe(CN)6]3− has 5 unpaired electrons. |
1. Both I and II are true.
2. I is true and II is false.
3. Both I and II are false.
4. I is false but II is true.
Subtopic: VBT, CFT & their Limitations |
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The correct statement among the following is:
| 1. | [Co(NH3)6]3+ and [Ni(NH3)6]2+, both are inner orbital complexes. |
| 2. | [Co(NH3)6]3+ and [Ni(NH3)6]2+ both are outer orbital complexes. |
| 3. | [Co(NH3)6]3+ is an inner orbital complex whereas [Ni(NH3)6]2+ is an outer orbital complex. |
| 4. | [Co(NH3)6]3+ is an outer orbital complex whereas [Ni(NH3)6]2+ is an inner orbital complex. |
Subtopic: VBT, CFT & their Limitations |
65%
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The number of unpaired electrons in the square planar [Pt(CN)4]2− ion is:
1. One
2. Zero
3. Two
4. Three
1. One
2. Zero
3. Two
4. Three
Subtopic: VBT, CFT & their Limitations |
75%
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Consider the following statements.
The correct statement(s) is/are
1. a, b only
2. b, c only
3. a, b, c
4. None of the above
| a. | The hexaquamanganese(II) ion contains five unpaired electrons, while the hexacyanomanganese(II) ion contains only one unpaired electron. |
| b. | [Mn(H2O)6]2+ is an outer sphere complex, and [Mn(CN)6]4− is an inner sphere complex. |
| c. | Arrangement of the electrons in [Mn(CN)6]4− is t2g5eg0. |
1. a, b only
2. b, c only
3. a, b, c
4. None of the above
Subtopic: VBT, CFT & their Limitations |
79%
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