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Q. No.Match the complexes from List I with their corresponding type of isomerism from List II:
Choose the correct from the options given below :
1. \(\text { A-I, B-III, C-IV, D-II }\)
2. \(\text { A-I, B-IV, C-III, D-II }\)
3. \(\text { A-II, B-IV, G-III, D-I }\)
4. \(\text { A-II, B-III,G-IV, D-I }\)
| List I (Complex) | List II (Type of isomerism) |
| A. \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{NO}_2\right)\right] \mathrm{Cl}_2\) | I. Solvate isomerism |
| B. \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Br}\) | II. Linkage isomerism |
| C. \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Cr}(\mathrm{CN})_6\right]\) | III. Ionization isomerism |
| D. \(\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3\) | IV. Coordination |
1. \(\text { A-I, B-III, C-IV, D-II }\)
2. \(\text { A-I, B-IV, C-III, D-II }\)
3. \(\text { A-II, B-IV, G-III, D-I }\)
4. \(\text { A-II, B-III,G-IV, D-I }\)
Subtopic: Isomerism in Coordination Compounds |
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Given below are two statements :
In the light of the above statements, choose the correct answer from the options given below:
1. Both Statement I and Statement II are False.
2. Statement I is True and Statement II is False.
3. Statement I is False but Statement II is True.
4. Both Statement I and Statement II are True.
| Statement I : | Both \(\left[\text{Co}\left(\text{NH}_3\right)_6\right]^{3+}\) and \(\left[\text{CoF}_6\right]^{3-}\) Complexes are octahedral but differ in their magnetic behaviour. |
| Statement II : | \(\left[\text{Co}\left(\text{NH}_3\right)_6\right]^{3+}\) is diamagnetic whereas \(\left[\text{CoF}_6\right]^{3-}\) is paramagnetic. |
1. Both Statement I and Statement II are False.
2. Statement I is True and Statement II is False.
3. Statement I is False but Statement II is True.
4. Both Statement I and Statement II are True.
Subtopic: VBT, CFT & their Limitations |
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Given below are two statements :
In light of the above statements, choose the correct answer from the options given below:
1. Both Statement I and Statement II are False.
2. Statement I is True but Statement II is False.
3. Statement I is false but Statement II is True.
4. Both Statement I and Statement II are True.
| Statement I: | \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}\) is a homoleptic complex, whereas \([Co(NH_3)_4 Cl_2]^+\) is a heteroleptic complex. |
| Statement II: | Complex \([Co(NH_3)_6]^{3+}\) has only one kind of ligands but \([Co(NH_3)_4 Cl_2]^+\) has more than one kind of ligand |
1. Both Statement I and Statement II are False.
2. Statement I is True but Statement II is False.
3. Statement I is false but Statement II is True.
4. Both Statement I and Statement II are True.
Subtopic: Introduction, Classification and Nomenclature |
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The correct 'spin only' magnetic moments of \([\text{CoF}_6]^{3-}\) and \(\left[\mathrm{Co}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}\) respectively, are:
1, 0 BM and 4.9 BM
2. 0 BM and 0 BM
3. 4.9 BM and 0 BM
4. 4.9 BM and 4.9 BM
1, 0 BM and 4.9 BM
2. 0 BM and 0 BM
3. 4.9 BM and 0 BM
4. 4.9 BM and 4.9 BM
Subtopic: VBT, CFT & their Limitations |
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Match the complex ions in List I with their corresponding hybridization in List II.
Choose the correct answer from the options given below:
1. A-IV, B-III, C-II, D-I
2. A-III, B-I, C-IV, D-II
3. A-I, B-II, C-III, D-IV
4. A-III, B-IV, C-II, D-I
| List -I (Complex ion) |
List -II (Hybridisation) |
||
| A. | \([\mathrm{Ni}(\mathrm{CN})_4]^{2-}\) | I. | \(s p^3 \) |
| B. | \(\mathrm{[CoF_6}]^{3-}\) | II. | \( d^2sp^3 \) |
| C. | \([\mathrm{Co}(\mathrm{C}_2 \mathrm{O}_4)_3 ]^{3-}\) | III. | \(s p^3d^2\) |
| D. | \(\mathrm{[NiCl_4}]^{2-}\) | IV. | \(dsp^2\) |
Choose the correct answer from the options given below:
1. A-IV, B-III, C-II, D-I
2. A-III, B-I, C-IV, D-II
3. A-I, B-II, C-III, D-IV
4. A-III, B-IV, C-II, D-I
Subtopic: VBT, CFT & their Limitations |
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The Crystal Field Stabilisation Energy (CFSE) and the 'spin only' magnetic moment of \(\mathrm{[FeF_6]^{3-}}\) ion respectively, are:
1. \(0~\Delta~\text{and}~5.9~\text{BM}\)
2. \(0~\Delta~\text{and}~1.73~\text{BM}\)
3. \(2.0~\Delta~\text{and}~5.9~\text{BM}\)
4. \(2.0~\Delta~\text{and}~1.73~\text{BM}\)
1. \(0~\Delta~\text{and}~5.9~\text{BM}\)
2. \(0~\Delta~\text{and}~1.73~\text{BM}\)
3. \(2.0~\Delta~\text{and}~5.9~\text{BM}\)
4. \(2.0~\Delta~\text{and}~1.73~\text{BM}\)
Subtopic: VBT, CFT & their Limitations |
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Ethylene diaminetetraacetate ion is a/an :
| 1. | Hexadentate ligand | 2. | Ambidentate ligand |
| 3. | Monodentate ligand | 4. | Bidentate ligand |
Subtopic: Ligands |
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Which of the following is not an ambidentate ligand?
| 1. | \(\mathrm{C_2O^{2-}_4}\) | 2. | \(\mathrm{SCN}^-\) |
| 3. | \(\mathrm{NO^{-}_2}\) | 4. | \(\mathrm{CN}^-\) |
Subtopic: Ligands |
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\([\mathrm{Mn}_2(\mathrm{CO})_{10}]\) and \([\mathrm{Co}_2(\mathrm{CO})_8]\) structures have:
A. Metal-Metal linkage
B. Terminal CO groups
C. Bridging CO groups
D. Metal in zero oxidation state
Choose the correct answer from the options given below:
1. Only A, B, C
2. Only B, C, D
3. Only A, C, D
4. Only A, B, D
A. Metal-Metal linkage
B. Terminal CO groups
C. Bridging CO groups
D. Metal in zero oxidation state
Choose the correct answer from the options given below:
1. Only A, B, C
2. Only B, C, D
3. Only A, C, D
4. Only A, B, D
Subtopic: Organometallic Complexes & their Uses |
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Homoleptic complex from the following complexes is:
1. Triamminetriaquachromium (III)
2. Potassium trioxalatoaluminate (III)
3. Diamminechloridonitrito-N-platinum (II)
4. Pentaamminecarbonatocobalt (III) chloride
1. Triamminetriaquachromium (III)
2. Potassium trioxalatoaluminate (III)
3. Diamminechloridonitrito-N-platinum (II)
4. Pentaamminecarbonatocobalt (III) chloride
Subtopic: Introduction, Classification and Nomenclature |
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