A buffer solution is prepared in which the concentration of NH3 is 0.30 M and the concentration of  NH4+  is 0.20 M. If the equilibrium constant, Kb for NH3 equals 1.8×10–5, then what is the pH of this solution? 
(log 1.8 = 0.25; log 0.67 = –0.176)

1.  9.43
2.  11.72
3.  8.73
4.  9.08

Subtopic:  Buffer |
 68%
Level 2: 60%+
AIPMT - 2011
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What conditions favor the formation of 2XY₄(g) in the reaction X₂(g) + 4Y₂(g) ⇋ 2XY₄(g), considering that the enthalpy change (ΔH) is negative?

1.  Low pressure and low temperature

2.  High temperature and low pressure

3.  High pressure and low temperature

4.  High temperature and high pressure

Subtopic:  Le Chatelier's principle |
 78%
Level 2: 60%+
AIPMT - 2011
Hints

Find the equilibrium constant K for the reaction:

NO₂(g) ⇌ ½N₂(g) + O₂(g)

Given:

N₂(g) + O₂(g) ⇌ 2NO(g), K₁

2NO(g) + O₂(g) ⇌ 2NO₂(g), K₂

1. 4K₁K₂
2. [1/(K₁K₂)]¹ᐟ²
3. 1/(K₁K₂)
4. 1/(2K₁K₂)
Subtopic:  Kp, Kc & Factors Affecting them |
 89%
Level 1: 80%+
AIPMT - 2011
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Links

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Calculate the hydrogen ion concentration, [\(\text{H}^+\)] (in \(\text{mol}/\text{L}\)), of a buffer solution prepared by mixing \(0.10 \text{ M}\) acetic acid (\(\text{CH}_3\text{COOH}\)) and \(0.20 \text{ M}\) sodium acetate (\(\text{CH}_3\text{COONa}\)), given that the acid dissociation constant (\(\text{K}_a\)) for acetic acid is \(1.8 \times 10^{-5}\):

1. \(3 . 5 \times 10^{- 4}\)
2. \(1 . 1 \times 10^{- 5}\)
3. \(1 . 8 \times 10^{- 5}\)
4. \(9 . 0 \times10^{- 6}\)

Subtopic:  Buffer |
 53%
Level 3: 35%-60%
AIPMT - 2010
Hints

The equilibrium reaction that doesn't have equal values for Kc and Kis: 

1. \(2NO(g) \rightleftharpoons N_2(g) + O_2(g)\)
2. \(SO_2(g) + NO_2(g) \rightleftharpoons SO_3(g) + NO(g)\)
3. \(H_2(g) + I_2(g) \rightleftharpoons 2HI (g)\)
4. \(2C(s) + O_2(g) \rightleftharpoons 2CO_2(g)\)

Subtopic:  Kp, Kc & Factors Affecting them |
 92%
Level 1: 80%+
AIPMT - 2010
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In a buffer solution containing an equal concentration of B- and HB, the Kb for B- is 10-10. pH of the buffer solution is:

1. 10 2. 7
3. 6 4. 4
Subtopic:  Buffer |
 72%
Level 2: 60%+
AIPMT - 2010
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Links

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Which of the following molecular hydrides acts as a Lewis acid?

1. NH3

2. H2O

3. B2H6

4. CH4

Subtopic:  Acids & Bases - Definitions & Classification |
 83%
Level 1: 80%+
AIPMT - 2010
Hints

The tendency of BF3, BCl3 and BBr3 to behave as Lewis acid decreases in the sequence:

1. BCl3>BF3>BBr3

2. BBr3>BCl3>BF3

3. BBr3>BF3>BCl3

4. BF3>BCl3>BBr3

Subtopic:  Acids & Bases - Definitions & Classification |
 66%
Level 2: 60%+
AIPMT - 2010
Hints

Which of the following molecules acts as a Lewis acid?
1. (CH3)3B
2. (CH3)2O
3. (CH3)3P
4. (CH3)3N
Subtopic:  Acids & Bases - Definitions & Classification |
 86%
Level 1: 80%+
AIPMT - 2009
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The ionization constant of ammonium hydroxide is 1.77 x 10-5 at 298 K. Hydrolysis constant of ammonium Chloride is:

1. 5.65 x 10-10 2. 6.50 x 10-12
3. 5.65 x 10-13 4. 5.65 x 10-12
Subtopic:  Salt Hydrolysis & Titration |
 75%
Level 2: 60%+
AIPMT - 2009
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