Select the correct option based on statements below:
Assertion (A): | The enthalpy of reaction remains constant in the presence of a catalyst. |
Reason (R): | A catalyst participating in the reaction forms a different activated complex and lowers down the activation energy but the difference in energy of the reactant and the product remains the same. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Column I | Column II | ||
A. | Catalyst alters the rate of reaction | 1. | Proper orientation is not there always |
B. | 2. | By lowering the activation energy | |
C. | Energetically favorable reactions are sometimes slow | 3. | Total probability is one |
D. | Area under the Maxwell-Boltzmann curve is constant | 4. | Refers to the fraction of molecules with energy equal to or greater than the activation energy |
Codes
A | B | C | D | |
1. | 2 | 4 | 1 | 3 |
2. | 3 | 1 | 4 | 2 |
3. | 1 | 4 | 3 | 2 |
4. | 3 | 4 | 1 | 2 |
The correct statements among the following is:
(a) | Catalyst provides an alternative pathway to the reaction mechanism |
(b) | Catalyst raises the activation energy |
(c) | A catalyst lowers the activation energy |
(d) | Catalyst alters enthalpy change of the reaction |
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, c)
Consider the following graph:
The point that represents the most probable kinetic energy is -
1. C
2. A
3. B
4. None of the above