Assertion (A): | NaCl reacts with concentrated H2SO4 to give colourless fumes with a pungent smell. But on adding MnO2, the fumes become greenish-yellow. |
Reason (R): | MnO2 oxidizes HCl to chlorine gas which is greenish-yellow. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Assertion (A): | SF6 cannot be hydrolysed but SF4 can be. |
Reason (R): | Six F-atoms in SF6 prevent the attack of H2O on sulphur atom of SF6 |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Assertion (A): | Both rhombic and monoclinic sulphur exist as S8 but oxygen exists as O2. |
Reason (R): | Oxygen forms pπ - pπ multiple bonds due to its small size and small bond length but pπ - pπ bonding is not possible in sulphur. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Assertion (A): | HI cannot be prepared by the reaction of KI with concentrated H2SO4. |
Reason (R): | HI has the lowest H—X bond strength among halogen acids. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Given below are two statements:
Assertion (A): | HNO3 makes iron passive. |
Reason (R): | HNO3 forms a protective layer of ferric nitrate on the surface of the iron. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
Given below are two statements:
Assertion (A): | N2 is less reactive than P4. |
Reason (R): | Nitrogen has more electron gain enthalpy than phosphorus. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Match the species given in Column I with the shape given in Column II and mark the correct option.
Column I | Column II | ||
A. | Its partial hydrolysis does not change the oxidation state of the central atom. | 1. | He |
B. | It is used in modern diving apparatus. | 2. | XeF6 |
C. | It is used to provide an inert atmosphere for filling electrical bulbs. | 3. | XeF4 |
D. | Its central atom is in sp3d2 hybridisation. | 4. | Ar |
Codes:
Options: | A | B | C | D |
1. | 1 | 4 | 2 | 3 |
2. | 1 | 2 | 3 | 4 |
3. | 2 | 1 | 4 | 3 |
4. | 1 | 3 | 2 | 4 |
Match the species given in Column I with the shape given in Column II and mark the correct option.
Column I (Specie) | Column II (Shape) | ||
A. | \(\mathrm{SF}_4\) | (I) | Tetrahedral |
B. | \(\mathrm{BrF}_3\) | (II) | Pyramidal |
C. | \(\mathrm{BrO}_3^{-}\) | (III) | Sea-saw shaped |
D. | \(\mathrm{NH}_4^{+}\) | (IV) | Bent T-shaped |
Codes:
A | B | C | D | |
1. | III | II | I | IV |
2. | III | IV | II | I |
3. | I | II | III | IV |
4. | I | IV | III | II |
Match the items in Columns I and II and mark the correct option.
Column I | Column II |
A. H2SO4 | 1. Highest electron affinity |
B. CCl3NO2 | 2. Chalcogen |
C. Cl2 | 3. Tear gas |
D. Sulphur | 4. Storage batteries |
Codes:
A | B | C | D | |
1. | 4 | 3 | 1 | 2 |
2. | 3 | 4 | 1 | 2 |
3. | 4 | 1 | 2 | 3 |
4. | 2 | 1 | 3 | 4 |
Match the compounds given in Column I with the hybridisation and shape given in Column II and mark the correct option.
Column I | Column II | ||
A | XeF6 | 1. | sp3d3 distorted octahedral |
B. | XeO3 | 2. | sp3d2 square planar |
C. | XeOF4 | 3. | sp3 pyramidal |
D. | XeF4 | 4. | sp3d2 square pyramidal |
Codes:
Options: | A | B | C | D |
1. | 1 | 3 | 4 | 2 |
2. | 1 | 2 | 4 | 3 |
3. | 4 | 3 | 1 | 2 |
4. | 4 | 1 | 2 | 3 |