For the following reaction, 
 H2(g)+I2(g)2HI(g) at 250°C,

The effect on the state of equilibrium on doubling the volume of the system will be:

1. Shift to the reactant side 2. Shift to the product side 
3. No effect on the state of equilibrium 4. Liquefaction of HI

Subtopic:  Le Chatelier's principle |
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Given an endothermic reaction:

CH4 (g) + H2O (g)  ⇋ CO (g) + 3H2 (g)

If the temperature is increased, then:

1. The equilibrium will not be disturbed.

2. The equilibrium will shift in the backward direction.

3. The equilibrium will shift in the forward direction.

4. None of the above.

Subtopic:  Le Chatelier's principle |
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Given a hypothetical reaction :
AB2g+12B2gAB3g; H=-x kJ
More  could be produced at equilibrium by :

1. Using a catalyst 2. Removing some of Bgas
3. Increasing the temperature 4. Increasing the pressure
Subtopic:  Le Chatelier's principle |
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Mark the conditions that favour the maximum product formation in the given reaction.
 A2 (g)  + B2 (g)   X2 (g), rH = -X k J  

1. Low temperature and High pressure
2. Low temperature and Low pressure
3. High temperature and High pressure
4. High temperature and Low pressure

Subtopic:  Le Chatelier's principle |
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The addition of a small amount of argon at a constant volume will not affect the equilibrium of the following reaction:

1. H2(g)+I2(g)⇌2HI(g)
2. PCl5(g)⇌ PCl3(g)+Cl2(g)
3. N2(g)+3H2(g)⇌2NH3(g)
4. The equilibrium will remain unaffected in all the three cases.

Subtopic:  Le Chatelier's principle |
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Consider the following reactions:

(i) COCl2 (g)  ⇋ CO (g) + Cl2 (g)

(ii) CO2 (g) + C (s)  2CO (g)

(iii) 2H2 (g) + CO (g)  CH3OH (g)


Which reaction(s) will shift in a backward direction when the pressure is increased?

1. Only (iii)

2. Only (ii)

3. Both (i) and (ii) 

4. None of the above.

Subtopic:  Le Chatelier's principle |
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(a) PCl5 (g) PCl3 (g) + Cl2 (g)

(b) CaO (s) + CO2 (g)   CaCO3 (s)

(c) 3Fe (s) + 4H2O (g)  Fe3O4 (s) + 4H2 (g)

The effect of an increase in the volume on the number of moles of products in the above-mentioned reactions would be, respectively:

1. a) Increase,  b) decrease, c) same

2. a) Decrease,  b) same, c) increase

3. a) Increase,  b) increase, c) same

4. a) Increase,  b) decrease, c) increase

Subtopic:  Le Chatelier's principle |
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For the reaction,

  PCl5(g) ⇌ PCl3(g) + Cl2 (g)

The forward reaction at constant temperature is favoured by:

1. Introducing an inert gas at a constant volume

2. Introducing chlorine gas at a constant volume

3. Introducing an inert gas at constant pressure

4. None of the above

Subtopic:  Le Chatelier's principle |
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Inert gas is added to the equilibrium PCl5(g⇌ PCl3(g) + Cl2(g) at constant pressure. The degree of dissociation will :

1. Remain unchanged

2. Decrease

3. Increase

4. Decrease or increase but cannot be predicted with certainty

Subtopic:  Le Chatelier's principle |
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According to Le-Chatelier's principle, adding heat to a solid ⇌ liquid equilibrium will cause the :

1. Temperature to increase

2. Temperature to decrease

3. Amount of liquid to decrease

4. Amount of solid to decrease

Subtopic:  Le Chatelier's principle |
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