The correct sequence of increasing orders of reactivity in nucleophilic addition reaction is:
1. Butanone < Propanone < Propanal < Ethanal
2. Butanone > Propanone > Propanal > Ethanal
3. Butanone < Propanal < Propanone < Ethanal
4. Propanal < Propanone < Ethanal < Butanone
Cannizzaro’s reaction is not given by:
1. | 2. | ||
3. | HCHO | 4. | CH3CHO |
The compound below is treated with a concentrated aqueous KOH solution. The products obtained are:
1. | |
2. | |
3. | |
4. |
What is the most suitable reagent for the below mentioned conversion?
\(\mathrm{CH_{3} — CH = CH — CH_{2} — \overset{\Large{O} \\~ ||}{C}—CH_{3} \rightarrow}\)
\(\mathrm{CH_{3} — CH = CH — CH_{2} — \overset{\Large{O} \\~ ||}{C}—OH}\)
1. Tollens' reagent
2. Benzoyl peroxide
3. \(\mathrm I_{2}\) and NaOH solution
4. Sn and NaOH solution
The conversions can be used for Clemmensen reduction are:
a. Benzaldehyde into benzyl alcohol.
b. Cyclohexanone into cyclohexane.
c. Benzoyl chloride into benzaldehyde.
d. Benzophenone into diphenyl methane.
1. | a and b | 2. | b and c |
3. | c and d | 4. | b and d |
Match the common names given in Column I with the IUPAC names given in Column II.
Column l (Common names) |
Column ll (IUPAC names) |
A. Cinnamaldehyde | 1. Pentanal |
B. Acetophenone | 2. Prop-2-enal |
C. Valeraldehyde | 3. 1-Phenylethanone |
D. Acrolein | 4. 3-Phenylprop-2-en-al |
Codes:
A | B | C | D | |
1. | 2 | 3 | 4 | 1 |
2. | 3 | 1 | 4 | 2 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 3 | 1 | 2 |
Match the acids given in Column I with their correct IUPAC names given in Column II and mark the appropriate option:
Column l (Acids) |
Column ll (IUPAC names) |
A. Phthalic acid | 1. Hexane-1,6-dioic acid |
B. Glutaric acid | 2. Benzene-1,2-dicarboxylic acid |
C. Succinic acid | 3. Pentane-1,5-dioic acid |
D. Adipic acid | 4. Butane-1,4-dioic acid |
Codes:
A | B | C | D | |
1. | 2 | 3 | 4 | 1 |
2. | 3 | 1 | 4 | 2 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 3 | 2 | 1 |
Match the reactions given in Column I with the suitable reagents given in Column II.
Column l (Reactions) |
Column ll (Reagents) |
A. Benzophenone → Diphenylmethane | 1. LiAlH4 |
B. Benzaldehyde → 1-Phenylethanol | 2. DlBAL-H |
C. Cyclohexanone → Cyclohexanol | 3. Zn(Hg)/Conc.HCl |
D. Phenyl benzoate → Benzaldehyde | 4. CH3MgBr |
Codes:
A | B | C | D | |
1. | 2 | 3 | 4 | 1 |
2. | 3 | 4 | 1 | 2 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 3 | 2 | 1 |
Match the example in Column I with the name of the reaction in Column II.
Column l (Example) |
Column ll (Reaction) |
A. |
1. Friedel-Crafts acylation |
B. |
2. HVZ reaction |
C. \(\small{2 \mathrm{CH}_{3} \mathrm{CHO} \stackrel{\mathrm{NaOH}}{\longrightarrow} \mathrm{CH}_{3}-\mathrm{CH}=\mathrm{CHCHO}}\) | 3. Aldol condensation |
D. |
4. Rosenmund Reaction |
A | B | C | D | |
1. | 2 | 3 | 4 | 1 |
2. | 3 | 1 | 4 | 2 |
3. | 3 | 4 | 1 | 2 |
4. | 4 | 1 | 3 | 2 |
Select the correct option based on the statements below:
Assertion (A): | The geometry of formaldehyde molecule is planar. |
Reason (R): | Formaldehyde molecule contains sp2 hybridized carbon atom. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |