1. | Alkaline copper sulphate |
2. | Alkaline solution of sodium potassium tartrate (Rochelle's salt) |
3. | Aqueous sodium citrate |
4. | Aqueous copper sulphate |
Statement I: | Benzoic acid produces effervescence on treatment with aq. \(\mathrm{NaHCO}_3\) |
Statement II: | The effervescence is due to the release of hydrogen gas. |
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List-I (Reagent) |
List-II (Name of the reaction) |
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A. | \(\mathrm{{H}_2, {Nd}-{Ba}S {O}_4}\) | I. | Gattermann-koch reaction |
B. | \(\mathrm{{(i) \; {CrO}_2 {Cl}_2, {CS}_2\\ (ii) {H}_2 {C}}}\) | II. | Reimer-Tiemann reaction |
C. | \(\mathrm{{CO, HCl, Anhyd.~\\ {AlCl}_3 / {CuCl}}}\) | III. | Etard reaction |
D. | \(\mathrm{{CHCl}_3, {NaOH}}\) | IV. | Rosenmund reduction |
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List I (Reaction) |
List II (Reagents/ Condition) |
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II.\(\mathrm{CrO}_3\) |
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III.\(\begin{aligned} & \mathrm{KMnO}_4 \\ & \mathrm{KOH}, \Delta \end{aligned}\) |
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IV. \(\mathrm{(i) \mathrm{O}_3\\ (ii) \mathrm{Zn}-\mathrm{H}_2 \mathrm{O}}\) |
1. | \(\mathrm{CH}_3 \mathrm{COCl} \xrightarrow[\Delta]{\mathrm{H}_2 \mathrm{O}} \mathrm{CH}_3 \mathrm{COOH}\) |
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3. | \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH} \xrightarrow[\text { (ii) } \mathrm{H}_3 \mathrm{O}^{\oplus}]{\text { (i) } \mathrm{KMnO}_{4}/\mathrm{OH^{-} }} \mathrm{CH}_3 \mathrm{COOH}\) |
4. | \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{OH} \xrightarrow{\mathrm{CrO}_3-\mathrm{H}_2 \mathrm{SO}_4} \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{COOH}\) |
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3. | 4. |