Statement I: | The boiling point of hydrides of Group 16 elements follow the order \(\text{H}_2 \text{O}>\text{H}_2 \text{Te}>\text{H}_2 \text{Se}>\text{H}_2 \text{S} .\) |
Statement II: | On the basis of molecular mass, H2O is expected to have lower boiling point than the other members of the group but due to the presence of extensive H-bonding in H2O, it has higher boiling point. |
List-I (Atom/Molecule) |
List-II (Property) |
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A. | Nitrogen | I. | Paramagnetic |
B. | Fluorine molecule | II. | Most reactive element in group 18 |
C. | Oxygen molecule | III. | Element with highest ionisation enthalpy in group 15 |
D. | Xenon atom | IV. | Strongest oxidising agent |
1. | A- III, B-I, C-IV, D-II | 2. | A-I, B-IV, C-III, D-II |
3. | A-II, B-IV, C-I, D-II | 4. | A-III, B-IV, C-I, D-II |
1. | \(\mathrm{PCl_5}\) possesses two different \(\mathrm{Cl-P-Cl}\) bond angles. |
2. | All five \(\mathrm{P-Cl}\) bonds are identical in length. |
3. | \(\mathrm{PCl_5}\) exhibits sp3d hybridisation. |
4. | \(\mathrm{PCl_5}\) consists of five \(\mathrm{P-Cl}\) (sigma) bonds. |
1. | The acidic strength of HX (X=F, Cl, Br and I) follows the order: HF > HCI > HBr >HI |
2. | Fluorine exhibits - 1 oxidation state whereas other halogens exhibit +1, +3, +5 and +7 oxidation states also. |
3. | The enthalpy of dissociation of F2 is smaller than that of Cl2. |
4. | Fluorine is stronger oxidising agent than chlorine. |
Sorry!! currently, the explanation for the question is not provided. If you need further help, please email at support@neetprep.com with subject: Explanation Missing for Question Id: 468846
Sorry!! currently, the explanation for the question is not provided. If you need further help, please email at support@neetprep.com with subject: Explanation Missing for Question Id: 468846
1. | \(\mathrm{PEt}_3\) and \(\mathrm{Asph}_3\) as ligands can form \(\mathrm{d} \pi-\mathrm{d} \pi\) bone with transition metals. |
2. | The \(\mathrm{N}-\mathrm{N}\) single bond is as strong as the \(\mathrm{P}-\mathrm{P}\) single bond. |
3. | Nitrogen has unique ability to form \(\mathrm{p \pi-p \pi}\) multiple bonds with nitrogen, carbon and oxygen. |
4. | Nitrogen cannot form \(\mathrm{d} \pi-\mathrm{p} \pi\) bond as other heavier elements of its group. |
List-I (Oxoacids of Sulphur) |
List-II (Bonds) |
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A. | Peroxodisulphuric acid | I. | Two S-OH, Four S=O, One S-O-S |
B. | Sulphuric acid | II. | Two S-OH, One S=O |
C. | Pyrosulphuric acid | III. | Two S-OH, Four S=O, One S-O-O-S |
D. | Sulphurous acid | IV. | Two S-OH, Two S=O |
Options: | A | B | C | D |
1. | III | IV | II | I |
2. | I | III | II | IV |
3. | III | IV | I | II |
4. | I | III | IV | II |
Assertion (A): | ICl is more reactive than I₂. |
Reason (R): | I-Cl bond is weaker than I-I bond. |
1. | (A) is False but (R) is True. |
2. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
3. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
4. | (A) is True but (R) is False. |
Statement I: | The boiling points of the following hydrides of group 16 elements increase in the order \(\mathrm{H}_{2} \mathrm{O}<\mathrm{H}_{2} \mathrm{~S}<\mathrm{H}_{2} \mathrm{Se}<\mathrm{H}_{2} \mathrm{Te} \) |
Statement II: | The boiling points of these hydrides increase with the increase in molar mass. |