When hydrolyzed with aqueous KOH, compounds that undergoes racemization are:
(i) | (ii) | CH3CH2CH2Cl | |
(iii) | (iv) |
1. | (i) and (ii) | 2. | (ii) and (iv) |
3. | (iv) only | 4. | (i) and (iv) |
The end product (C) in the below-mentioned reaction is:
\(H_3C-Br\xrightarrow{\bf KCN }A\xrightarrow{ \bf H_3O^+~~}B\xrightarrow[\bf\text{Ether}]{~~LiAlH_4~~}C\)
Which of the following compounds undergoes nucleophilic substitution reaction most easily?
1. | 2. | ||
3. | 4. |
Consider the reactions:
(i) | \(\small{{(CH_3)}_2CHCH_2Br\ \xrightarrow[]{C_2H_5OH}{(CH_3)}_2CHCH_2OC_2H_5 + HBr}\) |
(ii) | \(\small{{(CH_3)}_2CHCH_2Br\ \xrightarrow[]{C_2H_5O^-}{(CH_3)}_2CHCH_2OC_2H_5 + Br^-}\) |
The mechanisms of reactions (i) and (ii) are, respectively:
The correct order of increasing C-X bond reactivity toward nucleophiles among the following is:
I | II | ||
III | \(\left(\mathrm{CH}_3\right)_3 \mathrm{C}-\mathrm{X}\) | IV | \(\left(\mathrm{CH}_3\right)_2 \mathrm{CH}-\mathrm{X}\) |
1. | I < II < IV < III | 2. | II < III < I < IV |
3. | IV < III < I < II | 4. | III < II < I < IV |
Which of the following reactions cannot form new carbon-carbon bonds?
1. Reimer-Tiemann reaction
2. Cannizaro reaction
3. Wurtz reaction
4. Friedel-Crafts acylation
\(C_6H_5CH_2Br \xrightarrow[2.~H_3O^+] {1.Mg,Ether}~\mathrm X, \)
The product 'X' in the above reaction is:
1. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{OH} \)
2. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_3 \)
3. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{C}_6 \mathrm{H}_5 \)
4. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{OCH}_2 \mathrm{C}_6 \mathrm{H}_5\)
For the following:
(i) I-
(ii) Cl-
(iii) Br-
The increasing order of nucleophilicity would be:
1. I-<Br-<Cl-
2. Cl-<Br-<I-
3. I- <Cl-<Br-
4. Br-<Cl-<I-