The number average molar mass and mass average molar mass of a polymer are respectively 30,000 and 40,000. The polydispersity index (PDI) of the polymer is

1.  -1

2.  0

3.  > 1

4.  < 1

 66%
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The charge/size ratio of a cation determines its polarising power. Which one of the following sequences represents the increasing order of the polarising power of the cationic species, K+, Ca2 +, Mg2+, Be2+?

1.  K+ < Ca2+ < Mg2+ < Be2+

2.  Be2< K2+ < Ca2+ < Mg2+

3.  Mg2+ < Be2+ < K+ < Ca2+

4.  Ca2+ < Mg2+ <Be+ < K+

 64%
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In an amino acid, the carboxyl group ionises at pKa1 = 2.34 and ammonium ion at pKa2 = 9.60. The isoelectric point of the amino acid is at pH

1.  4.32

2.  3.34

3.  9.46

4.  5.97

 57%
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0.40 g of helium in a bulb at a temperature of T K had a pressure of p atm. When the bulb was immersed in a water bath at temperature 50 K more than the first one, 0.08 g of gas had to be removed to restore the original pressure. T is

1.  500 K

2.  400 K

3.  600 K

4.  200 K

 59%
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What percentage of glucopyranose is found at equilibrium in the aqueous solution?

1.  64%

2.  36%

3.  100%

4.  50%

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Which of the following is correctly arranged in order of increasing weight?

1.  0.0105 equivalent of H2C2O4. 2H2O<0.625g of Fe<0.006g atom of Ag<6.0×1021 atoms of Zn

2.  0.625 g of Fe < 0.0105 equivalent of H2C2O4 2H2O<6.0×1021 atoms of Zn<0.006g atoms of Ag

3.  0.625 g of Fe<6.0×1021 atoms of Zn<0.006 g atoms of Ag<0.0105 equivalent of H2C2O4.2H2O

4.  0.0105 equivalent of H2C2O4. 2H2O < 0.006 g atoms of Ag<6.0×1021 atoms of Zn<0.625 g of Fe

 60%
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The correct order of basic strength of the following are:

1.  I > II > IV > III

2.  IV > III > II > I

3.  II > III > IV > I

4.  III> IV> II> I

 55%
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If for a given substance, melting point is T8 and freezing point is TA then correct variation of entropy by graph between entropy changes:

1.  

2.  

3.  

4.  

 54%
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When a mixture of 1-hexanol and hexanoic acid in diethyl ether is shaken with an aqueous NaHC03solution, then which of the following is right distribution? 
       

1.  a

2.  b

3.  c

4.  d

 57%
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S and S for the reaction, , are 30.56 KJ mol-1 and 66.00 Jk-1 mol-1respectively. The temperature at which the free energy change for the reaction will be zero change for the reaction will be zero, is

1.  3528 K

2.  463 K

3.  73 K

4.  144 K

 61%
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