The vapour pressure of toluene is 59.1 torr at 313.75 K and 298.7 torr at 353.15 K. Calculate, the molar heat of vaporisation.

1. 37888 J mol^-1

2. 27188 J mol^-1

3.  12834 J mol^-1

4. 571328 J mol^-1

Which of the following pairs exhibit positive deviation from Raoult's law?
 

(i) Chloroform and Acetone

(ii) Carbon disulphide and Acetone

(iii) Ethanol and Acetone

(iv) Phenol and Aniline

1. i and ii

2. ii and iii

3. i and iv

4. ii and iv

A solution of acetone in ethanol:

1. Shows a negative deviation from Raoult's law.

2. Shows a positive deviation from Raoult's law.

3. Behaves like a near ideal solution.

4. Obeys Raoult's law.

The correct statement regarding a solution of two components A and B exhibiting positive deviation from ideal behaviour is :

1. Benzene + Toluene

2. Acetone + Chloroform

3. Chloroethane + Bromoethane

4. Ethanol + Acetone