Which is the correct representation for Nernst equation ?

1. \(E_{\mathrm{RP}}=E_{\mathrm{RP}}^{\circ}+\frac{0.059}{\mathrm{n}} \log \frac{[\text { oxidant }]}{[\text { reductant }]}\)

2. \(E_{\mathrm{OP}}=E_{\mathrm{OP}}^{\circ}-\frac{0.059}{\mathrm{n}} \log \frac{[\text { oxidant }]}{[\text { reductant }]}\)

3. \(E_{\mathrm{OP}}=E_{\mathrm{OP}}^{\circ}+\frac{0.059}{\mathrm{n}} \log \frac{[\text { reductant }]}{[\text { oxidant }]}\)

4. All of the above

The voltage of the cell given below increases with: 

Cell: Sn(s) + 2Ag⁺(aq) → Sn²⁺(aq) + 2Ag(s)

1. Increase in size of the silver rod.

2. Increase in the concentration of Sn²⁺ ions.

3. Increase in the concentration of Ag⁺ ions.

4. None of the above.

Which graph correctly correlates E_cell as a function of concentrations for the cell (for different values of M and M') ?

$\mathrm{Zn}\left(\mathrm{s}\right) + {\mathrm{Cu}}^{2+}\left(M\right) \stackrel{ }{\to }{\mathrm{Zn}}^{2+}(M\text{'}) + \mathrm{Cu}\left(\mathrm{s}\right);$
$E_{\mathrm{cell}}^{\circ } = 1.10 \mathrm{V}$
$X-\mathrm{axis} : {\log }_{10}\frac{\left[{\mathrm{Zn}}^{2+}\right]}{\left[{\mathrm{Cu}}^{2+}\right]}, Y-\mathrm{axis} : E_{\mathrm{cell}}$

1.                         2. 
3.                         4. 

The solution of CuSO₄ in which copper rod is immersed is diluted to 10 times, the reduction electrode potential:

1. increases by 0.030 V

2. decreases by 0.030 V

3. increases by 0.059 V

4. decreases by 0.059 V

The change in reduction potential of a hydrogen electrode when its solution initialy at pH = 0 is neutralised to pH = 7, is a/an-