For the reductidon of silver ions with copper metal, the standard cell potential was found to be + 0.46 V at 250C. The value of standard Gibbs energy(G0) will be ;
(F = 96500 Cmol-1)
1. -89.0 KJ
2. -89.0 J
3. -44.5 KJ
4. -98.0 KJ
When NaCl solution is electrolysed using Pt electrodes then pH of solution
1. Increases
2. Decreases
3. Remains same
4. Firstly increases and then decreases
If the E°cell for a given reaction has a negative value, which of the following gives correct relationships for the values of G° and Keq ?
(1) G° >0; Keq< 1
(2) G° >0; Keq>1
(3) G° < 0; Keq> 1
(4) G° <0; Keq< 1
Standard free energies of formation (in kJ/mol) at 298 K are -237.2, -394.4 and -8.2 for H2O(l), CO2(g) and pentane (g), respectively. The value of E°cell for the pentane-oxygen fuel cell is
(1) 1.968 V
(2) 2.0968 V
(3) 1.0968 V
(4) 0.0968 V