What are the geometries of \([Ni(CO)_4]\) and \([Ni(PPh_3)_2Cl_2]\) respectively?

1. Both square planar.

2. Tetrahedral and square planar, respectively.

3. Both tetrahedral.

4. Square planar and tetrahedral, respectively.

Which one of the following high spin complexes has the largest crystal field stabilization energy?

1.  ${\left[\mathrm{Cr}{\left({\mathrm{H}}_2\mathrm{O}\right)}_6\right]}^{2+}$

2.  ${\left[\mathrm{Cr}{\left({\mathrm{H}}_2\mathrm{O}\right)}_6\right]}^{3+}$

3.  ${\left[\mathrm{Mn}{\left({\mathrm{H}}_2\mathrm{O}\right)}_6\right]}^{2+}$

4.  ${\left[\mathrm{Mn}{\left({\mathrm{H}}_2\mathrm{O}\right)}_6\right]}^{3+}$

It is an experimental fact that DMG + Ni(ll)salt + ${\mathrm{NH}}_4\mathrm{OH}$ $\to$ Red precipitate Which of the following is wrong about this red precipitate?

(1)  It is a non-ionic complex

(2)  It has a square planar geometry

(3)  It has tetrahedral geometry

(4)  It is a diamagnetic complex

According to Crystal Field Theory (CFT), the compound, among the following, that forms a colored complex is:

1. [Ti(H₂O)₆]⁴⁺
2. [Cr(NH₃)₆]³⁺
3. K[V(F)₆]
4. (NH₄)₂[TiCl₆]

Among i. [Co(NH₃)₆]CI₃ , ii. [Ni(NH₃)₆]CI₂ , iii. Cr(H₂O)₆]CI₃ , iv. [Fe(H₂O)₆]CI₂, the diamagnetic complex is-

1. i

2. ii

3. iii

4. iv

For which of the following complexes IUPAC names is not correctly assigned?

1.  $\mathrm{Na}\left[\mathrm{Pt}\left({\mathrm{NH}}_3\right)\mathrm{BrCl}\left({\mathrm{NO}}_2\right)\right]$-Sodium amminebromidochlorido nitrito-N-pIatinate(II)

2.  $\left[{\mathrm{CuCl}}_2{\left(\mathrm{O} = \mathrm{C}{\left({\mathrm{NH}}_2\right)}_2\right)}_2\right]$-Dichlorobis (dicarboxido tetraamine) copper (II)

3.   ${\left[{\mathrm{PtCl}}_3\left({\mathrm{\eta }}^2 - {\mathrm{C}}_2{\mathrm{H}}_4\right)\right]}^{-}$ —Trichlorido (${\mathrm{\eta }}^2$ — ethylene) platinate(ll) ion

4.  ${\left[\mathrm{Fe}\left(\mathrm{Cl}\right){\left(\mathrm{CN}\right)}_4\left({\mathrm{O}}_2\right)\right]}^{4-}$—Chloridotetracynosuperoxoferrate (II) ion

The Crystal Field Stabilization Energy (CFSE) and the spin-only magnetic moment in Bohr Magneton (BM) for the complex ${\mathrm{K}}_3\left[\mathrm{Fe}{\left(\mathrm{CN}\right)}_6\right]$ are, respectively,

1.  $0.0{∆}_0 \mathrm{and} \sqrt{35} \mathrm{BM}$

2.  $-2.0{∆}_0 \mathrm{and} \sqrt{3} \mathrm{BM}$

3.  $-0.4{∆}_0 \mathrm{and} \sqrt{24} \mathrm{BM}$

4.  $-2.4{∆}_0 \mathrm{and} \sqrt{0} \mathrm{BM}$

${\mathrm{Zn}}^{2+} + 4{\mathrm{NH}}_3 \rightleftharpoons {\left[\mathrm{Zn}{\left({\mathrm{NH}}_3\right)}_4\right]}^{2+}$. the concentration of free ${\mathrm{Zn}}^{2+}$ ions in a solution of the complex ion ${\left[\mathrm{Zn}{\left({\mathrm{NH}}_3\right)}_4\right]}^{2+}$ can be increased significantly by the addition of

1.  ${\mathrm{H}}_2\mathrm{O}$

2.  HCl(aq)

3.  ${\mathrm{NH}}_3\left(\mathrm{aq}\right)$

4.  ${\mathrm{NH}}_4\mathrm{Cl}\left(\mathrm{aq}\right)$

Other than the X-ray diffractions, how could be the following pairs of isomers be distinguished from one another by;

$\left[\mathrm{Cr}{\left({\mathrm{NH}}_3\right)}_6\right] \left[\mathrm{Cr}{\left({\mathrm{NO}}_2\right)}_6\right] \mathrm{and}$$\left[\mathrm{Cr}{\left({\mathrm{NH}}_3\right)}_4{\left({\mathrm{NO}}_2\right)}_2\right] \left[\mathrm{Cr}{\left({\mathrm{NH}}_3\right)}_2{\left({\mathrm{NO}}_2\right)}_4\right]$
1.  Cryoscopic method

2.  Measurement of molar conductance

3.  Measuring magnetic moments

4.  Observing their colors

The hybridizations of [Ni(CO)₄] and [Cr(H₂O)₆]³⁺, respectively, are : 

1. sp³ and d³sp²

2. dsp² and d²sp³

3. sp³ and d²sp³

4. dsp²  and sp³d²