The energies of ${\mathrm{d}}_{\mathrm{xy}} \mathrm{and} {{\mathrm{d}}_{\mathrm{z}}}^2$ orbitals in octahedral and tetrahedral transition metal complexes are such that

1. $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) > \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in both tetrahedral and octahedral complexes

2. $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) < \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in both tetrahedral and octahedral complexes

3. $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) > \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in tetrahedral but $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) < \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in octahedral complexes

4. $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) < \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$  in tetrahedral but $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) > \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in octahedral complexes   

The number of geometrical isomers of [CrCl₂en(NH₃)₂] are:
[en-ethylenediamine]

The geometry and the number of the unpaired electron(s) of \([MnBr_{4}]^{2-}\), respectively, are:

The complex that can exhibit optical activity among the following is:

1. [CoCl₆]^3-

2. [Co(en)CI₄]^-

3. cis-[Co(en)₂Cl₂]⁺

4. trans-[Co(en)₂Cl₂]⁺ 

2.335 g of compound X (empirical formal CoH₁₂N₄Cl₃) upon treatment with excess AgNO₃ solution produces 1.435 g of a white precipitate. The primary and secondary valences of cobalt in compound X, respectively are:

[Given Atomic mass: Co = 59, Cl = 35.5, Ag = 108]

The geometry and magnetic property of ${\left[{\mathrm{NiCl}}_4\right]}^{2-}$, respectively, are

1.  Tetrahedral, Paramagnetic

2.  Tetrahedral, Diamagnetic

3.  Square planar, Paramagnetic

4.  Square planar, Diamagnetic  

Among
(i) [Cr(en)₃]³⁺
(ii) trans-[Cr(en)₂Cl₂]⁺
(iii) cis-[Cr(en)₂Cl₂]⁺
(iv) [Co(NH₃)₄Cl₂]⁺
the optically active complexes are-

1. (i), (ii) and (iii)

2. (i) and (iii)

3. (ii) and (iii)

4. (ii) and (iv)

Among the following complexes, the one that can exist
as facial(fac) and meridional(mer) isomer is:

Hybridization and geometry of ${\left[\mathrm{Ni}{\left(\mathrm{CN}\right)}_4\right]}^{2-}$ are

1.  $s{p}^{2}d$ and tetrahedral

2.  $s{p}^3$ and square planar

3.  $s{p}^3$ and tetrahedral

4.  $ds{p}^2$ and square planar

The total number of geometrical isomers possible for an octahedral complex of $\left[{\mathrm{MA}}_2{\mathrm{B}}_2{\mathrm{C}}_2\right]$ are:
(M = transition metal; A, B and C are monodentate ligands)