What is the major product of the following reaction?

${\mathrm{H}}_2\mathrm{C}=\mathrm{CH}-{\mathrm{CH}}_2-\mathrm{OH} \underset{\mathrm{excess}}{\overset{\mathrm{HBr}}{\to }} \mathrm{Product}$

1.  ${\mathrm{CH}}_3-\stackrel{\mathrm{Br}}{\stackrel{|}{\mathrm{CH}}}-{\mathrm{CH}}_2-\mathrm{Br}$

2.  ${\mathrm{H}}_2\mathrm{C}=\mathrm{CH}-{\mathrm{CH}}_2-\mathrm{Br}$

3.  ${\mathrm{CH}}_3-\stackrel{\mathrm{Br}}{\stackrel{|}{\mathrm{CH}}}-{\mathrm{CH}}_2-\mathrm{OH}$

4.  ${\mathrm{CH}}_3-\stackrel{OH}{\stackrel{|}{\mathrm{CH}}}-{\mathrm{CH}}_2-\mathrm{OH}$

$\stackrel{\mathrm{NBS}}{\to }$(A)$\stackrel{{\mathrm{CH}}_3\mathrm{SNa}}{\to }$(B), Product (B) is:

1.

2.  

3. 

4. None of the above

Which of the following reactant will not favour nucleophilic substitution reaction ?

1. 

2. Ph-Br

3. ${\mathrm{CH}}_3-\underset{{\mathrm{CH}}_3}{\overset{{\mathrm{CH}}_3}{\underset{\left|}{\overset{\right|}{\mathrm{C}}}}}-{\mathrm{CH}}_2-\mathrm{Br}$

4. All of the above

Rank the following in order of decreasing rate of solvolysis with aqueous ethanol (fastest $\to$slowest)

1. 2>1>3

2. 1>2>3

3. 2>3>1

4. 1>3>2

Which of the following alkyl halide undergo rearrangement in S_N1 reaction?

1. $\begin{array}{ccccccc}{\mathrm{CH}}_3& -& \underset{{\mathrm{CH}}_3}{\underset{|}{\stackrel{{\mathrm{CH}}_3}{\stackrel{|}{\mathrm{C}}}}}& -& \underset{\mathrm{I}}{\underset{|}{\mathrm{CH}}}& -& {\mathrm{CH}}_3\end{array}$

2.  

3.  

4. All of these

$\mathrm{Cl}-{\mathrm{CH}}_2-\underset{{\mathrm{CH}}_3}{\overset{{\mathrm{CH}}_3}{\underset{\left|}{\overset{\right|}{\mathrm{C}}}}}-{\mathrm{CH}}_2-{\mathrm{CH}}_2-\mathrm{Cl}+{\mathrm{I}}^{-}$
Product; Major product of this reaction is:-

1.$\mathrm{I}-{\mathrm{CH}}_2-\underset{{\mathrm{CH}}_3}{\overset{{\mathrm{CH}}_3}{\underset{\left|}{\overset{\right|}{\mathrm{C}}}}}-{\mathrm{CH}}_2-{\mathrm{CH}}_2-\mathrm{Cl}$

2. $\mathrm{Cl}-{\mathrm{CH}}_2-\underset{{\mathrm{CH}}_3}{\overset{{\mathrm{CH}}_3}{\underset{\left|}{\overset{\right|}{\mathrm{C}}}}}-{\mathrm{CH}}_2-{\mathrm{CH}}_2-\mathrm{I}$

3. ${\mathrm{H}}_2\mathrm{C}=\stackrel{{\mathrm{CH}}_3}{\stackrel{|}{\mathrm{C}}}-{\mathrm{CH}}_2-{\mathrm{CH}}_2=\mathrm{Cl}$

4. $\mathrm{Cl}-{\mathrm{CH}}_2-\underset{{\mathrm{CH}}_3}{\overset{{\mathrm{CH}}_3}{\underset{\left|}{\overset{\right|}{\mathrm{C}}}}}-{\mathrm{CH}}_2={\mathrm{CH}}_2$

Which nitro derivative of haloarene is most reactive towards nucleophilic substitution reaction?

1.

2.

3.

4.

Debromination of meso-dibromobutane gives mainly

1. n-butane

2. 1-butene

3. Cis-2-butene

4. Trans-2-butene

The products of reaction of alcoholic silver nitrite with ethyl bromide are :

1. Ethane

2. Ethene

3. Ethyl alcohol

4. Nitroethane

Identify (Z) in the following reaction sequence:

C₂H₅I $\underset{\mathrm{KOH}}{\overset{\mathrm{Alcoholic}}{\to }}$(X) $\underset{}{\overset{{\mathrm{Br}}_2}{\to }}$(Y) $\stackrel{\mathrm{KCN}}{\to }$(Z):

1. CH₃-CH₂-CN     

2. $\underset{\mathrm{CN}}{\underset{|}{{\mathrm{CH}}_2}}-\underset{\mathrm{CN}}{\underset{|}{{\mathrm{CH}}_2}}$

3. $\underset{Br}{\underset{|}{{\mathrm{CH}}_2}}-\underset{\mathrm{CN}}{\underset{|}{{\mathrm{CH}}_2}}$     

4. $\underset{\mathrm{CN}}{\underset{|}{\mathrm{CH}}}=\underset{\mathrm{CN}}{\underset{|}{\mathrm{CH}}}$