Two isomeric ketones 3-Pentanones and 2-pentanone can be distinguished by
1. I2/NaOH only
2. NaHSO3 only
3. NaCN/HCl
4. Both of (a) and (b)
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The reagent used for the separation of acetaldehyde from acetophenone is
1. NaHSO3
2. C6H5NHNH2
3. NH2OH
4. NaOH and I2
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Among acetic acid, phenol and n-hexanol which one of the following compound will react with NaHCO3 solution to give sodium salt and CO2?
1. Acetic acid
2. n-hexanol
3. Acetic acid and phenol
4. Phenol
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The following reaction,
Is known by the name
1. Friedel-Crafts reaction
2. Perkins reaction
3. Acetylation reaction
4. Schotten-Baumann reaction
Cannizaro’s reaction is not given by _____________.
1.
2.
3. HCHO
4.
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Match the common names given in Column I with the IUPAC names given in Column II.
Column I Column II
(Common names) (IUPAC names)
(i) Cinnamaldehyde (a) Pentanal
(ii) Acetophenone (b) Prop-2-enal
(iii) Valeraldehyde (c) 4-Methylpent-3-en-2-one
(iv) Acrolein (d) 3-Phenylprop-2-enal
(v) Mesityl oxide (e) 1-Phenylethanone
1. (i)-(d), (ii)-(e), (iii)-(a), (iv)-(b), (v)-(c)
2. (i)-(c), (ii)-(d), (iii)-(e), (iv)-(b), (v)-(a)
3. (i)-(a), (ii)-(d), (iii)-(b), (iv)-(c), (v)-(e)
4. (i)-(d), (ii)-(e), (iii)-(c), (iv)-(a), (v)-(b)
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Match the acids given in Column I with their correct IUPAC names given in Column II and mark the appropriate option.
Column I (Acids) |
Column I (IUPAC names) |
||
(i) | Phthalic acid | (a) | Hexane-1,6-dioic acid |
(ii) | Oxalic acid | (b) | Benzene-1,2-dicarboxylic acid |
(iii) | Succinic acid | (c) | Pentane-1,5-dioic acid |
(iv) | Adipic acid | (d) | Butane-1,4-dioic acid |
(v) | Glutaric acid | (e) | Ethane-1,2-dioic acid |
1. (i) — (a), (ii) — (b), (iii) — (c), (iv) — (d), (v) — (e)
2. (i) — (b), (ii) — (e), (iii) — (d), (iv) — (a), (v) — (c)
3. (i) — (b), (ii) — (a), (iii) — (d), (iv) — (e), (v) — (c)
4. (i) — (a), (ii) — (e), (iii) — (c), (iv) — (b), (v) — (d)
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Match the reactions given in Column I with the suitable reagents given in Column II.
Column I (Reactions) |
Column II (Reagents) |
||
(i) | Benzophenone → Diphenylmethane | (a) | LiAlH4 |
(ii) | Benzaldehyde → 1-Phenylethanol | (b) | DIBAL—H |
(iii) | Cyclohexanone → Cyclohexanol | (c) | Zn(Hg)/Conc. HCl |
(iv) | Phenyl benzoate → Benzaldehyde | (d) | CH3MgBr |
1. (i) — (a), (ii) — (b), (iii) — (d), (iv) — (c)
2. (i) — (b), (ii) — (c), (iii) — (a), (iv) — (d)
3. (i) — (c), (ii) — (d), (iii) — (a), (iv) — (b)
4. (i) — (d), (ii) — (c), (iii) — (b), (iv) — (a)
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Match the example given in Column I with the name of the reaction in Column II.
|
Column I |
|
Column II |
(i) |
(a) |
Friedel Crafts acylation |
|
(ii) |
(b) |
HVZ reaction |
|
(iii) |
(c) |
Aldol condensation |
|
(iv) |
(d) |
Cannizaro’s reaction |
|
(v) |
(e) |
Rosenmund’s reduction |
|
(vi) |
(f) |
Stephen’s reaction |
1. (i) — (c), (ii) — (a), (iii) — (d), (iv) — (b), (v) — (f), (vi) — (e)
2. (i) — (b), (ii) — (c), (iii) — (a), (iv) — (d), (v) — (f), (vi) — (e)
3. (i) — (a), (ii) — (b), (iii) — (c), (iv) — (d), (v) — (e), (vi) — (f)
4. (i) — (e), (ii) — (d), (iii) — (a), (iv) — (b), (v) — (f), (vi) — (c)
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What is the major organic product formed from the following reaction?
1. | 2. | ||
3. | 4. |
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