The temperature of the system decreases in an
(1) Adiabatic compression
(2) Isothermal compression
(3) Isothermal expansion
(4) Adiabatic expansion
Mark the correct statement
(1) For a chemical reaction to be feasible, ΔG should be zero
(2) Entropy is a measure of order in a system
(3) For a chemical reaction to be feasible, ΔG should be positive
(4) The total energy of an isolated system is constant
Which of the following is not a state function
(1) Internal energy
(2) Enthalpy
(3) Work
(4) Entropy
The work done in ergs for the reversible expansion of one mole of an ideal gas from a volume of 10 litres to 20 litres at 25°C is
(1) -
(2) -
(3)-
(4)
An ideal gas expands in volume from 1 × 10–3 m3 to 1 × 10–2 m3 at 300 K against a constant pressure of 1 × 105 Nm–2. The work done is [AIEEE 2004]
(1) 270 kJ
(2) –900 kJ
(3) –900 J
(4) 900 kJ
Mixing of non-reacting gases is generally accompanied by
(1) Decrease in entropy
(2) Increase in entropy
(3) Change in enthalpy
(4) Change in free energy
An irreversible process occuring isothermally in an isolated system leads to
(1) Zero entropy
(2) An increase in the total entropy of the system
(3) A decrease in the total entropy of the system
(4) None of these
Enthalpy and entropy change for a chemical reaction are –2.5 × 103 cal and 7.4 cal deg–1 respectively. Reaction at 298 K is -
(1) Spontaneous
(2) Reversible
(3) Irreversible
(4) Non-spontaneous
The entropy changed involved in the conversion of 1 mole of liquid water at 373 K to vapour at the same temperature will be [MP PET 2002]
(1) 0.119 kJ
(2) 0.109 kJ
(3) 0.129 kJ
(4) 0.120 kJ
When a liquid boils, there is [JIPMER 2002]
(1) An increase in entropy
(2) A decrease in entropy
(3) An increase in heat of vaporization
(4) An increase in free energy