Select the correct statement (s)-
(a) The C.N. of cation occupying a tetrahedral hole is 4.
(b) The C.N. of cation occupying a octahedral hole is 6.
(c) In schottky defects, density of the lattice decreases,
(A) a,b
(B) b,c
(C) a,b,c
(D) a,c
Which arrangement of electrons leads to anti-ferromagnetism?
(1) ↑↑↑↑
(2) ↑↓↑↓
(3) Both (a) and (b)
(4) None of these
Among the following types of voids. which one is the largest void:-
(A) Triangular system
(B) Tetragonal system
(C) Monoclinic system
(D) Octahedral
The ratio of cations to anion in a closed pack tetrahedral is:
(a) 0.714
(b) 0.225
(c) 0.02
(d) none of these
The most efficient packing of similar spheres is obtained in
1. the simple cubic system and the body centered cubic system
2. the simple cubic system and the hexagonal close packed system
3. the face centered cubic system and the hexagonal close packed system
4. the body centered cubic system and the face centered cubic system
Frenkel defect is noticed in:
(a) AgBr
(b) ZnS
(c) Agl
(d) all of these
How many octahedral and tetrahedral holes are present per unit cell in a face centred cubic arrangement of atoms?
(1) 8,4
(2) 1.2
(3) 4.8
(4) 2.1
Choose the correct matching sequence from the possibilities given
(a) Crystal defect | (i) AB AB AB. . . . type crystal |
(b) hcp | (ii) Covalent crystal |
(c) CsCl | (iii) Frenkel |
(d) Diamond | (iv) Face centered in cube |
(e) NaCl | (v) Body centered in cube |
(a) | (b) | (c) | (d) | (e) | |
(1) | (iii) | (i) | (ii) | (v) | (iv) |
(2) | (iii) | (i) | (v) | (ii) | (iv) |
(3) | (iii) | (v) | (i) | (ii) | (iv) |
(4) | (v) | (iii) | (iv) | (ii) | (i) |
An element (atomic mass = 100 g mole) having BCC structure has unit cell edge 400 . The density of the element is (number of atom bcc(z)=2)
1. 2.144g/cm3
2. 5.2g/cm3
3. 7.289g/cm3
4. 10.376g/cm3
The appearance of color in solid alkali metal halides is generally due to:-
1. Frankel Defect
2. Interstitial Defect
3. F-Centres
4. Schottky Defect