F2 gas can’t be obtained by the electrolysis of any F-1salt because-

(A) Fluorine is the strongest reducing agent

(B) Fluorine is the strongest oxidising agent.

(C) Fluorine easily combine with atmospheric O2

(D) All

Subtopic:  Electrode & Electrode Potential |
 79%
NEET - 2011
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If the E°cell for a given reaction has a negative value then which of the following gives the correct relationships for the values of G° and Keq?

(a) G° < 0;Keq > 1

(b) G° < 0; Keq < 1

(c) G°> 0; Keq < 1

(d) G° > 0; Keq > 1

Subtopic:  Relation between Emf, G, Kc & pH |
 72%
NEET - 2011
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Acetic acid has Ka = 1.8 × 10–5 while formic acid had Ka = 2.1 × 10–4. What would be the magnitude of the emf of the cell

Pt(H2) 0.1M acetic acid+0.1M sodium acetate0.1M formic acid+0.1M sodium formate Pt(H2) at 25°C

(1) 0.0315 volt

(2) 0.0629 volt

(3) 0.0455 volt

(4) 0.0545 volt

Subtopic:  Nernst Equation |
 65%
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What will be the quantity of iron deposited by ferrous and ferric ion by 1F (Fe = 56)

(1) 14g, 9.3 g                                          

(2) 28g, 18.6 g

(3) 56g, 37.2g                                         

(4) None of these

Subtopic:  Faraday’s Law of Electrolysis |
 88%
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The unit of specific conductance is:

1. ohm-1 cm-1 2. ohm cm
3. ohm cm-1 4. ohm-1 cm
Subtopic:  Conductance & Conductivity |
 82%
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What is the value of 

pKb (CH3COO- ) 
if λm0= 390 & λm = 7.8 
for 0.04 of a CH3COOH at 25°C

(A) 9.3                                               

(B) 9.2

(C) 4.7                                               

(D) 4.8

Subtopic:  Conductance & Conductivity |
 59%
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Given that a certain electric current generates 0.504 grams of hydrogen in 2 hours. How many gram of mass of copper can be liberated by the same current when applied for the same duration in a solution of CuSO4?

1. 12.7

2. 16

3. 31.8

4. 63.5

Subtopic:  Faraday’s Law of Electrolysis |
 68%
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The metal that cannot be produced upon reduction of its oxide by aluminium is :

1. K 2. Mn
3. Cr 4. Fe
Subtopic:  Electrode & Electrode Potential |
 73%
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 E0 for the reaction 
Fe + Zn2+ = Zn + Fe2+ is  0.35 V.
The given cell reaction is- 

(A) Feasible                                                                  

(B) Not feasible

(C) In equilibrium                                                         

(D) None

Subtopic:  Electrode & Electrode Potential |
 79%
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Adiponitrile is manufactured electrolytically from acrylonitrile. The reaction is as follows:
CH2= CHCN  CN  (CH2 )4  CN

How many kg of adiponitrile (molecular mass = 108) is produced in 9.65 hr using a current of 3750 A with 80 % efficiency?

1. 30 kg                                               

2. 58 kg

3. 60 kg                                               

4. 80 kg

Subtopic:  Faraday’s Law of Electrolysis |
 61%
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