Which of the two ions from the list given below have the geometry that is explained by the same hybridisation of orbitals, ${\mathrm{NO}}_2^{-},{\mathrm{NO}}_3^{-},{\mathrm{NH}}_2^{-},{\mathrm{NH}}_4^{-}, \mathrm{and} {\mathrm{SCN}}^{-}$ ?

1.  ${\mathrm{NH}}_4^{-} \mathrm{and} {\mathrm{NO}}_3^{-}$

2.  ${\mathrm{SCN}}_{}^{-} \mathrm{and} {\mathrm{NH}}_2^{-}$

3.  ${\mathrm{NO}}_2^{-} \mathrm{and} {\mathrm{NH}}_2^{-}$

4.  ${\mathrm{NO}}_2^{-} \mathrm{and} {\mathrm{NO}}_3^{-}$

Which of the following has the minimum bond length?

In which one of the following species the central atom has the type of hybridization which is not the same as that present in the other three ?

1. ${\mathrm{SF}}_4$

2. ${\mathrm{I}}_3^{-}$

3. ${\mathrm{SbCl}}_5^{2-}$

4. ${\mathrm{PCl}}_5$

According to the MO theory, which of the following lists ranks the nitrogen species in terms of increasing bond order?

1. $N_2^{-}<N_2<N_2^{2-}$

2. $N_2^{2-}<N_2^{-}<N_2$

3. $N_2<N_2^{2-}<N_2^{-}$

4. $N_2^{-}<N_2^{2-}<N_2$

The correct order of \(\mathrm{C-O}\) bond length among \(\mathrm{CO},\mathrm{CO}_3^{2-},\) and \(\mathrm{CO_2}\) is :

1. \(\mathrm{CO}_2<\mathrm{CO}_3^{2-}<\mathrm{CO} \)
2. \(\mathrm{CO}<\mathrm{CO}_3^{2-}<\mathrm{CO}_2 \)
3. \(\mathrm{CO}_3^{2-}<\mathrm{CO}_2<\mathrm{CO} \)
4. \(\mathrm{CO}<\mathrm{CO}_2<\mathrm{CO}_3^{2-}\)

Which of the following is not a correct statement?

Which of the following is not isostructural with SiCl₄?

1. $SC{l}_4$

2. $S{O}_4^{2-}$

3. $P{O}_4^{3-}$

4. $N{H}_4^{+}$

Which of the following diatomic molecular species has only $\mathrm{\pi }$ bonds according to Molecular Orbital Theory?

1.  Be₂

2.  O₂

3.  N₂

4.  C₂

The number of sigma ($\mathrm{\sigma }$) and pi ($\mathrm{\pi }$) bonds in pent-2-en-4-yne is:

1. 13 $\mathrm{\sigma }$ bonds and no $\mathrm{\pi }$ bond

2. 10 $\mathrm{\sigma }$ bonds and 3 $\mathrm{\pi }$ bonds

3. 8 $\mathrm{\sigma }$ bonds and 5 $\mathrm{\pi }$ bonds

4. 11 $\mathrm{\sigma }$ bonds and 2 $\mathrm{\pi }$ bonds

The correct structure of tribromo octoxide is: