An amine reacts with ${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{SO}}_2\mathrm{Cl}$ and the product is soluble in alkali, amine is:

(1) $1°$

(2) $2°$

(3) $3°$

(4) all of these

Which of the following will give a primary amine on hydrolysis?

(1) Nitroparaffin

(2) Alkyl cyanide

(3) Oxime

(4) Alkyl isocyanate

Mark the correct statement:

(1) Methyl amine is slightly acidic.

(2) Methyl amine is less basic than ammonia.

(3) Methyl amine is a stronger base than ammonia.

(4) Methyl amine forms salts with alkali.

Which one of the following amines will not react with ${\mathrm{HNO}}_2$ acid to give nitrogen?

(1) ${\mathrm{CH}}_3{\mathrm{NH}}_2$

(2) ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{NH}}_2$

(3) ${\mathrm{CH}}_3-\underset{\underset{{\mathrm{CH}}_3}{|}}{\mathrm{C}}\mathrm{H}-{\mathrm{NH}}_2$

(4) 

What is decreasing order of basicity of p-, s-, t-ethyl amines and ${\mathrm{NH}}_3$ in aqueous medium ?

(1) NH₃>C₂H₅NH₂>(C₂H₅)₂NH>(C₂H₅)₃N

(2) (C₂H₅)₃N>(C₂H₅)₂NH>C₂H₅NH₂>NH₃

(3) (C₂H₅)₂NH>C₂H₅NH₂>NH₃>(C₂H₅)₃N

(4) (C₂H₅)₂NH>(C₂H₅)₃N>C₂H₅NH₂>NH₃

Urea on heating with ethanol gives:

1. Urethane

2. Urea alcohol

3. Ureides

4. None of the above

Alkyl nitrite on reduction with Sn/HCl gives:

1. Alcohol

2. Hydroxylamine

3. Both (a) and (b)

4. Hydrazine

Which of the following compounds is expected to be the most basic?

(1) Aniline

(2) Ethylamine

(3) Hydroxylamine

(4) Methylamine

The action of nitrous acid on a primary amine gives:

(1) nitroalkane

(2) alkyl nitrite

(3) alcohol

(4) secondary amine

The reaction,

${\mathrm{CH}}_3\mathrm{CN}+4\mathrm{H}\stackrel{\mathrm{Na}/{\mathrm{C}}_2{\mathrm{H}}_5\mathrm{OH}}{\to }{\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{NH}}_2$ is called:

1. Hofmann's bromamide reaction

2. Mendius reaction

3. Sabatier reaction

4. None of the above