The decreasing order of the acidic nature of ${\mathrm{H}}_2{\mathrm{SO}}_4 \left(\mathrm{I}\right), {\mathrm{H}}_3{\mathrm{PO}}_4 \left(\mathrm{II}\right), \mathrm{and} {\mathrm{HClO}}_4 \left(\mathrm{III}\right)$ is:

1. I>II>III

2. I>III>II

3. III>I>II

4. III>II>I

The number of H⁺ ions present in 1cm³ of a solution whose pH is 10 is

1. ${10}^{-10}$

2. ${10}^{-13}$

3. $6.02\times {10}^{10}$

4. $6.02\times {10}^{13}$

The Ka value of formic acid and acetic acid are respectively $1.77\times {10}^{-4}$ and $1.75\times {10}^{-5}$. The ratio of the acid strength of 0.1 N acids is

1. 0.1

2. 0.3

3. 3.178

4. 100

ZnS is not precipitated by passing H₂S in an acidic medium but CuS is precipitated. The reason for it is

1. ${\mathrm{K}}_{\mathrm{sp}} \mathrm{CuS}<<{\mathrm{K}}_{\mathrm{sp}} \mathrm{ZnS}$

2.${\mathrm{K}}_{\mathrm{sp}} \mathrm{CuS}>>{\mathrm{K}}_{\mathrm{sp}} \mathrm{ZnS}$

3. ${\mathrm{K}}_{\mathrm{sp}} \mathrm{CuS}={\mathrm{K}}_{\mathrm{sp}} \mathrm{ZnS}$

4. None of these

Consider the following acids:

I. HCN

II. CH₃COOH

III. HCOOH

IV. Cl-CH₂COOH

The correct order of strength is

1. II>III>I>IV

2. IV>II>III>I

3. IV>III>II>I

4. III>II>IV>I

The hydrogen ion concentration is 0.2 M ethanoic acid $({\mathrm{K}}_{\mathrm{C}}=2\times {10}^{-5} \mathrm{mol} {\mathrm{dm}}^{-3})$ is approximately

1. ${10}^{-4}$

2. $2\times {10}^{-2}$

3. $2\times {10}^{-6}$

4. $2\times {10}^{-3}$

The pH of a solution made by mixing 50 mL of 0.01 M barium hydroxide solution with 50 mL of H₂O is

Find the molar solubility of Fe(OH)₃ in a buffer solution that 0.10 M in NH₄Cl and 0.10 M in NH₃. If ${\mathrm{K}}_{\mathrm{b}} \left({\mathrm{NH}}_3\right)=1.8\times {10}^{-5}$ and ${\mathrm{K}}_{\mathrm{sp}} \left[\mathrm{Fe}{\left(\mathrm{OH}\right)}_3\right]=2.6\times {10}^{-39}.$

1. $4.458\times {10}^{-25} \mathrm{M}$

2. $3.458\times {10}^{-25} \mathrm{M}$

3. $2.229\times {10}^{-24} \mathrm{M}$

4. $4.458\times {10}^{-22} \mathrm{M}$

A base dissolved in water yields a solution with a hydroxyl ion concentration of \(0.05 \mathrm{~mol}~ \mathrm{litre}^{-1}\). The solution is:

1. Basic

2. Acid

3. Neutral

4. Either acid or neutral

Given that the ionization constant (\(K_a\)) of acetic acid \((\text{CH}_3\text{COOH})\) is \(1.7 \times 10^{-5}\) and the concentration of hydrogen ions (\(\text{H}^+ \)) is \(3.4 \times 10^{-4}\), what is the initial concentration of acetic acid (\(\text{CH}_3\text{COOH}\))?

1. \(3 . 4 \times \left(10\right)^{- 4}\)

2. \(3 . 4 \times \left(10\right)^{- 3}\)

3. \(6 . 8 \times \left(10\right)^{- 4}\)

4. \(6 . 8 \times \left(10\right)^{- 3}\)