Which of the following statements is correct for a spontaneous process?

1. The entropy of the system always increases.

2. The free energy of the system always increases. 

3. The total entropy change is always negative. 

4. The total entropy change is always positive.

Which one of the following has the maximum entropy of vaporization?

(Assuming all are in the liquid phase)

1. Water  

2. Toluene 

3. Diethyl ether 

4. Acetone  

Which of the following is not an endothermic reaction?

1. Combustion of methane

2. Decomposition of water

3. Dehydrogenation of ethane or ethylene

4. Conversion of graphite to diamond

Which of the following statements is false?

1. Work is a state function.

2. Temperature is a state function.

3. Density is a state function.

4. Entropy is state function.

Standard molar enthalpy of formation of ${\mathrm{CO}}_2$ is equal to

1. Zero

2. The standard molar enthalpy of combustion of gaseous carbon.

3. The sum of standard molar enthalpies of formation Of CO and ${\mathrm{CO}}_2$

4. The standard molar enthalpy of combustion of carbon (graphite)

Which one of the following reactions obeys  ∆ H ≠ ∆ E.?

The Gibbs free energy is defined as

1. G=H$-$T.S

2. G=H+T.S

3. G=E$-$ T.S

4. G=E+ T.s

Which of the following statement is true for $∆$G?

1. It is always proportional to $∆$H

2. It may be less than or greater than or equal to $∆$H

3. It is always greater than $∆$H

4. It is always less than $∆$H

The free energy change $(∆G°)$ is negative when -

1. The surroundings do no electrical work on the system.

2. The surroundings do electrical work on the system.

3. The system does electrical work on the surroundings.

4. The system does no electrical work on the surroundings.

In a constant volume calorimeter 3.5g of a gas

(mol.wt.28) was burnt in excess O${}_2$ at 298 K. The

increase in temperature is 0.45 K due to combus-

tion, If Heat capacity of calorimeter is 2.5 kJ/K

the value of $∆$E is

1. 90 KJ/m

2. 9 kJ/m

3. 45 kJ/m

4. 18 kJ/m